可冷凝颗粒物排放受到烟气脱硫技术的调节,在典型的工业设施中
Xiwen Song1, Jinrun Yi1, Yuanzheng Chen1
1Department of Environmental Science and Engineering, Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Fudan University, Shanghai 200433, China.
Journal of hazardous materials
|February 11, 2025
概括
工业烟气脱硫 (FGD) 系统显著改变可凝结颗粒物 (CPM) 的组成. 控制氨滑落对于减少FGD工艺后的CPM排放至关重要.
科学领域:
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
- 大气化学 大气化学
背景情况:
- 可凝结颗粒物 (CPM) 排放日益令人担忧,往往超过工业来源的可过颗粒物.
- 空气污染控制装置,特别是烟气脱硫 (FGD) 系统对CPM特征的影响需要进一步调查.
研究的目的:
- 系统地调查各种FGD系统如何影响CPM排放特征.
- 了解FGD处理前后的CPM组件的化学转化.
主要方法:
- 在22个工业场所进行了现场测量.
- 分析的重点是无机CPM的组成,特别是水溶性离子,在FGD的入口和出口.
- 前体转化 (NH3,HCl,SO3) 与离子度相关.
主要成果:
- 无机CPM,主要是水溶性离子,在FGD前后表现出不同的组成.
- 由于差异离子去除,部分石灰石膏湿FGD系统将CPM从富含化物转变为富含硫酸盐.
- 氨湿和活性焦的FGD系统导致富含氨的CPM,这是由于无效的氨滑动控制.
结论:
- FGD过程在CPM中诱导了显著的化学特异性转换.
- 控制氨滑动对于减轻CPM排放至关重要,特别是在脱硫过程后.
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