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设计,合成,和一个环保的甲基二二胺衍生物的tribological行为

Fan Yang^1,2, Zenghui Li^1,2, Hongmei Yang²

¹School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China.

International journal of molecular sciences

|February 13, 2025

概括

一种环保的添加剂,甲基三醇胺衍生物 (MeBz-2-C18),在合成基油中显示出增强的储存和三角学性能. 与商业替代品相比,它提供了优越的金属表面吸附和减少摩擦.

科学领域:

材料科学材料科学材料科学
部落学 (tribology) 是一个学科.
绿色化学绿色化学

背景情况:

多功能添加剂对于提高滑剂性能和环境兼容性至关重要.
开发具有卓越功能性质的环保添加剂仍然是关键的研究目标.

研究的目的:

设计和合成一个环保的甲基三醇胺衍生物 (MeBz-2-C18).
为了评估MeBz-2-C18在合成基油中的储存稳定性和tribological行为.
为了比较其性能与商用酸胺盐 (T406) 的性能.

主要方法:

使用NMR,HR-MS,FT-IR和TGA合成和对MeBz-2-C18的结构特征.
储存稳定性和三角学性能 (磨损痕直径) 的比较评估.
使用SEM-EDS,XPS和DFT计算进行微机制分析.

主要成果:

与T406相比,MeBz-2-C18表现出优越的热和储存稳定性.
在0.5%的重量中,MeBz-2-C18减少了21.6%的磨损痕直径,超过了T406的13.9%的减少.
DFT和表面分析显示,MeBz-2-C18在金属表面上的吸附力更强,并在摩擦时突破优先的胺键.

结论:

合成的MeBz-2-C18表现出卓越的三角学特性和增强的稳定性.
它的优越性能归因于更强的表面吸附和有效的摩擦修饰机制.
MeBz-2-C18 是一个有前途的环保添加剂,用于高级滑应用.

关键词:

胺基衍生品胺基衍生品甲基二三醇的使用方法多功能添加剂多功能添加剂合成碳化合物合成碳化合物部落学行为是部落学行为.

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