稀土元素从水中吸附使用活性废物灰
Tijana Radojičić1, Katarina Trivunac1, Marija Vukčević1
1Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia.
Materials (Basel, Switzerland)
|February 13, 2025
概括
废弃物飞灰被修改为制造酸聚合物,用于从水中去除稀土元素 (REEs). 这种方法实现了高达95%的REE去除,为废物管理和环境修复提供了可持续的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 废物管理 废物管理
背景情况:
- 由于新技术,对稀土元素 (REEs) 的需求不断增加.
- 对REE对环境和健康的影响的认识有限.
- 需要有效的方法来从水中去除REE.
研究的目的:
- 从废弃飞灰中合成无机酸聚合物.
- 研究这些聚合物的应用,以从水中去除选定的REEs (Gd3+,Y3+,Sc3+).
- 探索改性灰在减少废物和建筑应用中的潜力.
主要方法:
- 废弃飞灰的性激活,以合成酸聚合物.
- 使用XRD和DRIFT光谱学对改性材料进行表征.
- 使用热力学和动力学参数对REE吸附的研究.
主要成果:
- 成功合成具有明显聚合物网络结构的酸聚合物.
- 观察石的形成,表明木灰的存在.
- 在单溶液和混合溶液中,Gd3+,Y3+和Sc3+具有高吸附效率 (高达95%).
- 据推测吸附机制涉及化学吸附和离子交换.
结论:
- 活性飞灰和木灰混合物是有效的吸附剂,用于REE去除.
- 该研究有助于理解REE环境修复和废物利用.
- 修改后的灰显示出作为建筑添加剂的潜在用途.
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