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相关概念视频

Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

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In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
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Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate02:21

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

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Alkenes can be dihydroxylated using potassium permanganate.  The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
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Oxidation and Reduction of Organic Molecules01:19

Oxidation and Reduction of Organic Molecules

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Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
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Thermal and Photochemical Electrocyclic Reactions: Overview01:26

Thermal and Photochemical Electrocyclic Reactions: Overview

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Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
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Radical Autoxidation01:20

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The oxidation of an organic compound in the presence of air or oxygen is called autoxidation. For example, cumene reacts with oxygen to form hydroperoxide. Autoxidation involves initiation, propagation, and termination steps. Many organic compounds are susceptible to autoxidation—especially ethers in the presence of oxygen, which form hydroperoxides. Even though this reaction is slow, old ether bottles contain small amounts of peroxide, which leads to laboratory explosions during ether...
2.1K
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9.8K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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由成熟诱导的嵌入形成的超稳定的支持氧化演变电催化剂

Wenjuan Shi1, Tonghao Shen2, Chengkun Xing1

  • 1State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, China.

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概括

一种新方法将催化剂嵌入氧化中,增强质子交换膜水电解器 (PEMWE) 的稳定性和效率. 这一突破支持以耐用,低负载的氧气进化催化剂的太瓦级生产.

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科学领域:

  • 材料科学
  • 电化学
  • 催化剂

背景情况:

  • 质子交换膜水电解器 (PEMWE) 技术需要高效,稳定和经济高效的氧化进化催化剂来实现太瓦规模的部署.
  • (Ir) 催化剂虽然活跃,但由于溶解,重新沉积,脱离和聚合,其稳定性较差.

研究的目的:

  • 在PEMWE中开发一种稳定催化剂的新策略.
  • 通过催化剂支持工程提高PEMWE的长期耐用性和效率.

主要方法:

  • 使用成熟诱导的嵌入策略将催化剂纳米粒子固定在氧化支上.
  • 使用冷电子断层扫描和全原子动力蒙特卡洛模拟来分析合成机制.
  • 为了评估催化剂的稳定性和性能,进行了加速衰老试验 (6000小时).

主要成果:

  • 嵌入策略成功地稳定了物种,防止了降解.
  • 合成的催化剂实现了低Ir负荷 (0.3 mg/cm2) 与高性能 (1.72V在3A/cm2).
  • 在电压降解率为1. 33μV/ h的情况下,证明了长期稳定性.

结论:

  • 通过超声波同步支持生长和Ir核化对于有效的催化剂嵌入至关重要.
  • 开发的嵌入式Ir催化剂为未来PEMWE系统中稳定和高效的氧气演变提供了有希望的解决方案.
  • 这种方法为大规模绿色生产所必需的成本效益和耐用催化剂铺平了道路.