混合阻燃剂对聚烯阻燃性能的双金属影响
Xiaojing Lv1, Jiehao Dong1, Minao Xia1
1International Sci. & Tech. Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, PR China.
Langmuir : the ACS journal of surfaces and colloids
|February 14, 2025
概括
一种新的混合阻燃剂 (MPA@ZrP-Zn) 显著增强聚烯.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 阻燃性是指阻燃性是指阻燃性.
背景情况:
- 聚烯 (PP) 复合材料缺乏足够的阻燃性,这是应用的关键限制.
- 内燃阻燃剂 (IFR) 依赖含量来抑制烟雾和炭火形成.
- 为PP开发有效的阻燃剂对于安全性和性能至关重要.
研究的目的:
- 为聚烯复合材料合成和评估一种新的混合阻燃剂 (MPA@ZrP-Zn).
- 调查阻燃机制,包括炭火形成和烟雾减少.
- 为了证明这种新材料在高性能应用中的潜力.
主要方法:
- 使用胺和植物酸进行MPA@ZrP-Zn的非共价合成.
- 将MPA@ZrP-Zn纳入聚烯,以制造PP复合材料 (PPZn30).
- 阻燃性测试包括UL-94,限制氧气指数 (LOI),总热释放率 (THR) 和峰值热释放率 (PHRR).
- 使用拉曼光谱法 (ID/IG比) 分析燃烧残留物.
主要成果:
- MPA@ZrP-Zn在PP复合材料中表现出极好的阻燃性能.
- 在UL-94测试中,PPZn30获得了V-0等级和33.5%的LOI.
- 与纯 PP 相比,THR (15.1%) 和 PHRR (54.2%) 的显著降低被观察到.
- 通过拉曼光谱学证实了增强的炭层石墨化,这归因于Zr-Zn双金属效应.
结论:
- 混合MPA@ZrP-Zn阻燃剂为提高PP阻燃性提供了一个有希望的策略.
- Zr-Zn的双金属效应有助于改善滴水抵抗和减少烟雾排放.
- 这些高性能PP复合材料在电器和能源汽车中具有潜在的应用.
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