从废物变成资源:开发LIBS方法,快速评估回收木材的质量
Diana Capela1, Sofia Pessanha2, Tomás Lopes1
1Center for Applied Photonics, INESC TEC, Rua do Campo Alegre 687, Porto 4169-007, Portugal; Departamento de Física e Astronomia, Faculdade de Ciências da Universidade do Porto, Rua do Campo Alegre 687, Porto 4169-007, Portugal.
Journal of hazardous materials
|February 14, 2025
概括
激光诱导分解光谱 (LIBS) 有效地检测木材废物中的危险污染物,提供快速的现场选方法. 这项技术支持可持续的废物管理,通过快速识别和修复受污染的材料.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 危险污染物阻碍了木材废物管理.
- 传统的检测方法是缓慢的,昂贵的,需要大量的样本准备.
- 激光诱导分解光谱 (LIBS) 提供了一个快速的现场替代方案,采用最小的样本准备.
研究的目的:
- 评估LIBS成像用于检测木材废物中的危险元素 (As, Ba, Cd, Cr, Cu, Hg, Pb, Sb, Ti).
- 开发和验证一个强大的LIBS方法论,用于定性元素分析.
- 评估LIBS在工业废物管理中的高通量选方面的潜力.
主要方法:
- 使用LIBS成像分析木材废弃物样本.
- 为了提高准确性,开发了一种使用每个元素三条光谱线的方法.
- 结果使用成像X射线光 (XRF) 和手持XRF系统进行了交叉验证.
- 在特定情况下使用ICP-MS分析来进一步验证发现.
主要成果:
- LIBS显示出强大的检测高度污染的木材废弃物样本的能力.
- 三行标准有效地减轻了光谱干扰和异常数据.
- 在大规模研究 (100个样本) 中,成功率超过88%.
- LIBS提供了可靠的元素选,与XRF方法相提并论.
结论:
- LIBS是一种能够快速,现场检测木材废物中危险污染物的技术.
- 开发的LIBS方法支持通过高效的材料选来实现可持续的废物管理.
- LIBS促进了污染木材废物的更快的识别和整治,改善了工业流程.
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