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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.9K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

16.8K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
16.8K
Formation of Complex Ions03:45

Formation of Complex Ions

23.2K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.1K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.1K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

62.1K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
62.1K

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LiFePO<sub>4</sub>/Nano-LLZTO Composite Cathodes for Enhanced Performance of Solid-State Lithium Batteries.

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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固态硫电池中的固体电解质和树突动力学

Chien-Yu Pan1, Guan-Liang Kuo1, Chia-Chen Li1

  • 1Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan.

ACS applied materials & interfaces
|February 15, 2025
PubMed
概括

改进复合固体电解质 (CSEs) 是安全的固态电池 (SSLB) 的关键. 在CSE中分散性差导致不均的充电和树的生长,导致电池故障.

科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 固态电池 (SSLB) 与传统的液体电解质电池相比,提供了更高的安全性.
  • 目前的SSLB通常由于固体电解质量的限制而表现较低.
  • 基于陶的复合固体电解质 (CSEs) 对于SSLB的发展至关重要.

研究的目的:

  • 调查基于陶的CSE中分散质量对固态硫电池 (SSLSB) 性能的影响.
  • 了解Li6.4La3Zr1.4Ta0.6O12 (LLZTO) 粒子分散在PVDF-HFP矩阵中的作用.
  • 确定与电解质量和树形成有关的SSLSB的故障机制.

主要方法:

  • 在PVDF-HFP矩阵中制备具有不同Li6.4La3Zr1.4Ta0.6O12 (LLZTO) 分散品质的CSE.
  • 使用准备好的CSE和硫阴极组装SSLSB.
  • 电化学阻抗光谱 (EIS) 和放松时间分布 (DRT) 分析.
  • 三电极配置,临界电流密度测试,现场光学显微镜和有限元模拟.

主要成果:

  • 低质量的CSE与LLZTO差的分散导致不均的收费运输.
关键词:
一个LLZTOTO.李·斯 (Li−S) 是一种存在的东西.树状的树状物固体电解质是一种固体电解质.固态电池是一种固态电池.

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  • 低标准的CSEs在电池循环过程中促进了显著的树形成.
  • 不均的电荷传输和树突的生长被确定为容量衰减和细胞衰竭的主要原因.
  • 虽然CSE可以抑制穿效应,但树的生长仍然是一个关键的挑战.
  • 结论:

    • 在CSEs中陶颗粒的分散质量极大地影响SSLSB的性能和寿命.
    • 统一的电荷传输和树突的抑制对于可靠的SSLSB运行至关重要.
    • 解决树的增长对于推进固态电池技术至关重要.