基于氧的共价有机框架作为一个关闭式光探针,用于在有机溶剂中检测微量水
Fengmin Cui1, Yingdi Zhang1, Benhai Liu1
1Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China. ias_ydu@njtech.edu.cn.
概括
新的基于氧的共价有机框架 (COF) 检测水分子. TFPT-DAPO-COF提供了一种敏感和选择性的方法来检测溶剂中的水,其检测极限很低.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 纳米技术纳米技术
背景情况:
- 氧衍生物以其独特的电子特性而闻名.
- 协价有机框架 (COF) 为各种应用提供可调节的结构.
- 分子内电荷转移 (ICT) 是影响光物理性质的关键现象.
研究的目的:
- 为了合成基于氧的新型COF (TFPB-DAPO-COF和TFPT-DAPO-COF).
- 调查这些COF的ICT特征及其对水分子的反应.
- 评估这些COF作为水检测传感器的潜力.
主要方法:
- 合成了TFPB-DAPO-COF和TFPT-DAPO-COF. 这两种组合.
- 谱分析用于研究ICT属性.
- 在接近溶剂 (例如THF) 中存在不同水度的光灭实验.
主要成果:
- 合成的基于色素的COF与母色素相比,显示出增强的ICT.
- 水分子与DAPO-COFs形成键,削弱ICT并降低光强度.
- TFPT-DAPO-COF对THF中的水表现出快速且高度选择性的反应,检测极限为0.0656%v/v.
结论:
- 基于氧的COF是水检测的有效光传感器.
- 光火机制与水度成正比.
- TFPT-DAPO-COF为敏感和选择性的分子水位传感提供了一个有前途的工具.
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