构建N,B联合合的碳纳米片与胺N-B位点,以促进离子储存
Tiantian Zhang1, Tian Tian1, Shengxu Kuai1
1Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China.
The Journal of chemical physics
|February 18, 2025
概括
和联合的碳纳米片通过改善离子储存和动力学来增强离子电池阳极. 这种新型材料为高效的储能应用提供了高容量和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 碳质材料是离子电池 (SIB) 的有希望的阳极,但面临着缓慢的动力学和容量衰减的挑战.
- 异原子兴奋剂可以增强碳材料中的离子吸附和活性位点,以提高电池性能.
研究的目的:
- 开发一种新的/联合化碳纳米板 (NB-CN),用于高效的离子 (Na+) 储存.
- 调查双重兴奋剂和层次性多孔性对SIB阳极性能的协同效应.
主要方法:
- 合成的/联合化碳纳米片 (NB-CN) 使用B化MIL-68作为前体.
- 在SIB中描述了材料的结构,组成和电化学性能.
- 使用NB-CN阳极和Na3V2(PO4) 3 / C阴极组装和测试了一个完整的电池.
主要成果:
- NB-CN表现出丰富的N-B键,促进了离子吸附和水友性.
- 2D多孔结构促进了快速的Na+转移动力学.
- 在0.1Ag-1下,NB-CN提供了307.1mAhg-1的高容量,并在8000次循环后在4Ag-1下保持了157mAhg-1.
- NB-CNs//Na3V2(PO4)3/C全细胞显示了实际应用的潜力.
结论:
- 和联合,结合层次性的多孔结构,显著提高离子储存性能.
- 开发的NB-CN材料显示出SIB阳极的优良容量,速率能力和循环稳定性.
- 这项研究为设计高性能离子电池的先进双碳材料提供了洞察力.
相关概念视频
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Overview
3.2K
Nitrous acid and nitric acids are two types of acids containing nitrogen, among which nitrous acid is weaker than nitric acid. Nitrous acid with a pKa value of 3.37 ionizes in water to give a nitrite ion and the hydronium ion.
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
3.2K
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism
3.7K
Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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