能源交换统计和非热异常状态的波动定理
Santiago Hernández-Gómez1,2,3, Francesco Poggiali1,3, Paola Cappellaro2,4
1CNR-INO, via Nello Carrara 1, I-50019 Sesto Fiorentino, Italy.
Physical review. E
|February 20, 2025
概括
研究人员将Jarzynski-Wójcik波动定理概括为非热状态. 确定了一个独特的能量尺度因子的条件,这对于理解散射量子系统中的能量交换至关重要.
科学领域:
- 量子热力学就是量子热力学.
- 统计力学就是统计力学.
- 非平衡的系统是不平衡的.
背景情况:
- 贾辛斯基-沃伊奇克波动定理描述了在热平衡状态下系统之间的能量交换.
- 这个定理依赖于与逆温度相关的特定能量比例因子.
- 消散量子动力学可以导致系统进入非热异常状态,从而挑战现有的定理.
研究的目的:
- 为了将Jarzynski-Wójcik波动定理概括为达到非热状态的消散量子系统.
- 在这些概括的场景中,确定一个独特的,与时间无关的能量规模因子的条件.
- 探索这些发现的物理解释和实验验证.
主要方法:
- 研究消散量子动力学. 研究消散量子动力学.
- 确定了一个足够的条件 (条件I) 存在一个独特的能量规模因子 (η*).
- 分析了能量交换分布的特征函数.
- 在单个空缺中心进行实验研究.
主要成果:
- 根据条件I,在非热状态下确定了一个独特的,与时间无关的能量量级因子 (η*).
- 条件我被证明与几乎完全失去初始状态的记忆相对应.
- 发现能量交换分布的特征函数在任何时间均等于1.
- 实验结果表明,针对从条件I.偏离的发现的稳定性.
结论:
- 一般化的Jarzynski-Wójcik定理为理解非热量子系统中的能量交换提供了一个框架.
- 识别的能量尺度因子 (η*) 是这些非平衡动态的一个关键参数.
- 这些发现对控制和预测开放量子系统中的能量交换有意义.
相关概念视频
Second Law of Thermodynamics
22.9K
In the quest to identify a property that may reliably predict the spontaneity of a process, a promising candidate has been identified: entropy. Processes that involve an increase in entropy of the system (ΔS > 0) are very often spontaneous; however, examples to the contrary are plentiful. By expanding consideration of entropy changes to include the surroundings, a significant conclusion regarding the relation between this property and spontaneity may be reached. In thermodynamic...
22.9K
Entropy
28.6K
Salt particles that have dissolved in water never spontaneously come back together in solution to reform solid particles. Moreover, a gas that has expanded in a vacuum remains dispersed and never spontaneously reassembles. The unidirectional nature of these phenomena is the result of a thermodynamic state function called entropy (S). Entropy is the measure of the extent to which the energy is dispersed throughout a system, or in other words, it is proportional to the degree of disorder of a...
28.6K
Entropy and the Second Law of Thermodynamics
2.7K
The second law of thermodynamics can be stated quantitatively using the concept of entropy. Entropy is the measure of disorder of the system.
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
2.7K
First Law of Thermodynamics
31.4K
Energy Conservation
31.4K
Statements of the Second Law of Thermodynamics
2.6K
The second law of thermodynamics can be stated in several different ways, and all of them can be shown to imply the others. The Clausius’ statement of the second law of thermodynamics is based on the irreversibility of spontaneous heat flow. It states that heat will not flow from the colder body to the hotter body unless some other process is involved. Additionally, as per the Kelvin’s statement, it is impossible to convert the heat from a single source into work without any other...
2.6K
Free Energy Changes for Nonstandard States
10.8K
The free energy change for a process taking place with reactants and products present under nonstandard conditions (pressures other than 1 bar; concentrations other than 1 M) is related to the standard free energy change according to this equation:
where R is the gas constant (8.314 J/K·mol), T is the absolute temperature in kelvin, and Q is the reaction quotient. This equation may be used to predict the spontaneity of a process under any given set of conditions.
Reaction Quotient...
where R is the gas constant (8.314 J/K·mol), T is the absolute temperature in kelvin, and Q is the reaction quotient. This equation may be used to predict the spontaneity of a process under any given set of conditions.
Reaction Quotient...
10.8K


