通过光谱测量利用银纳米颗粒作为平台传感器的方法,在大米中进行非色谱无机物种化
Francisco Eduardo Holanda Lima1, Francisco Luan Fonsêca da Silva2, Abdullah Abkar Akhdhar3
1Laboratório de Estudos em Química Aplicada (LEQA), Departamento de Química Analítica e Físico-Química, Universidade Federal do Ceará, Campus do Pici, 60455-760, Fortaleza, CE, Brazil.
Food chemistry
|February 20, 2025
概括
使用银纳米粒子 (Ag@PEG) 的新传感器可以准确测量米中的有毒无机 (iAs). 这种更简单,更快速,更环保的方法有助于监测这一重要主食中的IA水平.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
- 食品安全 食品安全
背景情况:
- 米是 (As) 的重要饮食来源,是一种有毒元素.
- 无机 (iAs) 是大米中发现的最有毒物种,需要精确的监测.
- 在大米中量化IA的传统方法可能是复杂和耗时的.
研究的目的:
- 开发和验证一种新型传感器平台,用于对大米中无机 (iAs) 的量化.
- 为了利用与聚乙烯糖醇 (Ag@PEG) 功能化的等离子银纳米粒子用于光谱光学iAs检测.
- 为现有分析技术提供更简单,更快,更低成本,更环保的替代方案.
主要方法:
- 使用聚乙烯糖醇 (Ag@PEG) 的等离子银纳米颗粒的功能化.
- 在大米样本中量化IA的光谱光度测量方法的开发.
- 使用经认证的参考材料 (SRM NIST 1568b) 进行验证,并与HPLC-ICP-MS进行比较.
主要成果:
- Ag@PEG传感器显示出良好的线性 (115 μg kg-1) 和对IA的高选择性.
- 达到0.66μg kg-1的检测极限 (LOD) 和1.99μg kg-1.1的量化极限 (LOQ).
- 方法验证显示了高准确性,从SRM中恢复了105%的IA,并且与HPLC-ICP-MS达成107%的一致.
结论:
- 拟议的Ag@PEG光谱测量方法提供了一种可靠和有效的手段,用于在米中量化IA.
- 这种传感器平台提供了一种实用且环保的方法,用于在大米中常规监测IA.
- 这些发现有助于确保食品安全,通过更好地评估大米中有毒含量.
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