范德瓦尔斯的非传统 (反) 铁电在范德瓦尔斯的IV组单基化物中
Fengrui Sui1, Yilun Yu1, Ju Chen2
1Key Laboratory of Polar Materials and Devices (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, China.
Nature communications
|February 20, 2025
概括
研究人员在一个中心对称材料 - - 化 (GeSe) 中发现了内在的平面外反铁电. 这一发现为铁电材料开辟了新的途径,因为它使以前被对称规则排除在外的材料中能够产生场诱导的铁电极化.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 铁电材料传统上需要非中心对称的晶体结构,这限制了新材料的发现.
- 范德瓦尔斯四组单基化物,如化 (GeSe),是中心对称的,阻止他们从传统的铁电应用.
研究的目的:
- 研究诱导中心对称范德瓦尔斯材料中的铁电的可能性.
- 探索化 (GeSe) 作为一种新型铁电半导体的潜力.
主要方法:
- 使用现场原子成像来观察结构扭曲.
- 执行电气测量以分析歇斯底里循环.
- 使用第一原则计算来确定极化特征.
主要成果:
- 在中心对称的GeSe半导体中观察到内在的平面外反铁电.
- 证实了由外部电场触发的反铁电-铁电相位过渡.
- 识别了垂直极化,证明了场诱导的铁电行为.
结论:
- 德化 (GeSe) 呈现出隐藏的外平面反铁电和场诱导的铁电极化,尽管它的中心对称性.
- 这一发现扩大了具有铁电性质的范德瓦尔斯层状半导体的类别.
- 这些发现表明,在其他中心对称范德瓦尔斯材料中实现铁电的潜在途径.
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