废核燃料储池排水中的纳米颗粒和体和
Thomas S Neill1, Katherine Morris1, Scott Harrison2
1Radioactive Waste Disposal and Environmental Remediation (RADER) National Nuclear User Facility and Williamson Research Centre, Department of Earth and Environmental Sciences, The University of Manchester, Manchester M13 9PL, UK.
Journal of hazardous materials
|February 21, 2025
概括
来自塞拉菲尔德遗留池中的放射性合物含有和纳米粒子. 这些颗粒与较大的聚合物结合,影响放射性核素的移动性,并为核退役的废物处理策略提供信息.
科学领域:
- 核化学和材料科学 核化学和材料科学
- 环境整治和废物管理
- 放射化学 放射化学是指辐射化学.
背景情况:
- 核废物中的合体在退役期间对放射性核素的移动性构成挑战.
- 塞拉菲尔德核设施需要检索和退役的遗留存储池和仓库.
- 了解水生工程环境中放射性核酸的长期命运至关重要.
研究的目的:
- 从塞拉菲尔德的60年历史的遗留池中特征化颗粒物.
- 在合相内研究放射性核素 (,) 的物种化和关联.
- 告知放射性废水处理和处置策略.
主要方法:
- 超过以分离合物分离物.
- 传输电子显微镜 (TEM) 用于纳米粒子成像.
- 动氨酸L3边缘X射线吸收光谱 (XAS) 用于物种分析 (和).
主要成果:
- 识别了与Mg-Al和Fe-氧化氧化物相相关的离散UO2类纳米颗粒 (5-10nm).
- 物种化揭示了U(IV) 氧化物纳米颗粒和化U(VI) 的混合物.
- 的物种化表明Pu(IV) 是主要的氧化状态,与聚合物相关.
结论:
- 放射性核素与较大的聚合体的关联表明伪合体的形成,解释了当前的过效率.
- 提供了对复杂,高水平放射性环境中的放射性核酸物种化和移动性的新理解.
- 为核电退役提供了改进的放射性废水处理和处理技术的信息.
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