一个高效的H2S耐受性氧化电催化剂,由易斯酸修饰器启用,用于燃料电池
Yu Yang1,2, Ye-Hua Wang1, Fei-Yue Gao1
1Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Nano letters
|February 21, 2025
概括
在-合金上用氧化制成的新催化剂为氧化反应提供了高性能. 这种先进的材料有效地耐受燃料电池中硫化 (H2S) 毒害.
科学领域:
- 催化剂是一种催化剂.
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
背景情况:
- 工业用燃料含有硫化 (H2S),它会毒害燃料电池中的催化剂.
- 将H2S去除到10亿分之一的水平至关重要,但困难且昂贵.
研究的目的:
- 开发一种耐受H2S的氧化反应 (HOR) 催化剂.
- 为了实现与催化剂相当的高性能.
主要方法:
- 在- (MoNi4) 合金上用化学方法将氧化 (Cr2O3) 接种在合金上.
- 使用催化剂表面相互作用研究H2S耐受性的机制.
主要成果:
- 复合 Cr2O3 / MoNi4 催化剂表现出极好的 H2S 耐受性.
- 催化剂实现了与碳 (Pt/C) 商业相提并论的HOR性能.
- 一个带有复合催化剂的燃料电池在没有停用的情况下存活了5ppm的H2S.
结论:
- 该Cr2O3涂层通过排斥硫化物离子来防止H2S中毒.
- 在催化剂表面吸附的基离子增强了HOR动力学.
- 这种新型催化剂为受H2S污染的燃料应用提供了一个有希望的替代方案.
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