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使用甲基利米达硫化盐进行快速类合成

Joey Lai1, Carlota Bahri1, Mai P Truong1

  • 1Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada.

Communications chemistry
|February 22, 2025
PubMed
概括

使用硫 (IV) 化物的新联方法提供了快速,经济高效的合成. 这种方法避免了净化和表皮化,有效地产生二和寡.

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Preparation and Reactions of Sulfides02:26

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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