在Fe3O4中的非线性磁性,通过选择性稀土替代诱导,增加其和磁化
Haining Li1, Masaki Kobayashi1,2, Sonju Kou3
1Department of Electrical Engineering and Information Systems, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Small (Weinheim an der Bergstrasse, Germany)
|February 24, 2025
概括
在氧化铁 (Fe3O4) 薄膜中的稀土欧 (Eu) 离子替代增强了磁性. 由于非对线磁性,四面体Eu替代显著增加了和磁化.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 磁力学 磁力学 是一种
背景情况:
- 在3D过渡金属氧化物中,稀土离子的替代可以通过旋转轨道合来控制磁性.
- 非线性磁性源于显著的旋转轨道合,影响材料的行为.
研究的目的:
- 为了研究Fe3O4薄膜中的选择性欧 (Eu3+) 替代.
- 通过受控的Eu3+合并来增强Fe3O4薄膜的磁性.
主要方法:
- 实验调查与密度函数理论相结合.
- 使用电电阻和价值带光辐射证实了位点选择性.
- 通过X射线吸收光谱学和X射线磁性圆形二元化进行表征.
主要成果:
- 在Fe3O4中进行四面体Eu3+替代,显著提高了和磁化 (MS) 到4.4μB/f.u. 由于非对线性. 由于非对线性.
- 八面体Eu3+替代导致减少了MS.
- 在四面体置换中,Eu3+磁矩对轨道磁矩和磁性异构性作出了积极的贡献.
结论:
- 关于四面体Eu3+替代Fe3O4.4的旋转配置的经验证据.
- 证明选择性取代作为设计具有增强MS的铁磁4f化合物的策略.
- 非线性磁力在观察到的磁性增强中起着至关重要的作用.
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