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Updated: May 26, 2025

Facile Preparation of 4-Substituted Quinazoline Derivatives
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Published on: February 15, 2016

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在Rh (II) /guanidine催化非对称的N-H键插入的DFT研究索胺胺的索胺 imines

Jiaying Xu1, Qi Wei1, Changwei Hu1

  • 1Key Laboratory of Green Chemistry and Technology, Ministry of Education, National and Local Joint Engineering Laboratory of Energy Plant Biofuel Preparation and Utilization, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, P. R. China. suzhishan@scu.edu.cn.

Organic & biomolecular chemistry
|February 24, 2025
PubMed
概括

这项研究揭示了性瓜尼丁和Rh (II) 催化剂是如何实现对光学活性氨基酸的合成而进行选择性N-H键插入的. 该机制涉及Rh-carbene形成和用于立体控制的性质子穿.

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