生物基CBM生成对高挥发性煤的微晶和功能群的影响
Aikuan Wang1,2, Qiang Huang1,2, Zhiyuan Yao1,2
1Key Laboratory of Coalbed Methane Resources & Reservoir Formation Process, Ministry of Education, China University of Mining & Technology, Xuzhou, 221008, China.
Heliyon
|February 24, 2025
概括
高挥发性煤的生物降解产生煤床甲 (CBM). 这一过程损害了煤炭.
科学领域:
- 地质化学 地质化学
- 微生物学 微生物学
- 有机石矿学 有机石矿学
背景情况:
- 煤床甲 (CBM) 的产生受有机物质的生物降解的影响.
- 了解生物基CBM机制需要分析煤炭的物理和化学变化.
研究的目的:
- 研究从高挥发性煤中产生生物 CBM 的过程.
- 分析生物降解对煤炭微晶和化学结构的影响.
主要方法:
- 使用高挥发性煤样本进行模拟实验.
- 用于微晶结构分析的X射线衍射 (XRD).
- 福里埃变换红外光谱 (FTIR) 用于化学结构分析.
主要成果:
- 在80天的时间里,生物基CBM的平均生成率为7.43mL/g.
- XRD显示了芳香层距离的增加和结构参数 (Lc,La,Nc) 的降低,表明损伤.
- FTIR揭示了酸碳化合物和甲基组的减少,含基和含氧组的增加.
结论:
- 高挥发性煤显示出生物 CBM 应用的潜力.
- 生物降解的副产品破坏了煤炭的微晶结构.
- 在早期的生物降解阶段,亚利法性碳化合物具有重要作用.
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