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Updated: May 26, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

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通过生物启发的C-S σ-键转化合成硫化物

Hongmei Liu1, Yuzhu Zheng1, Ke-Lin Xian1

  • 1Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, 430074, China.

Chemistry (Weinheim an der Bergstrasse, Germany)
|February 25, 2025
PubMed
概括

这项研究引入了一种新的生物启发的σ-键转化反应,模仿S-adenosylmethionine (SAM) 循环. 该方法有效地将有机硫化物和酒精转化为有价值的化合物,提供新的合成途径.

关键词:
C−O/C−S 的转化.一个SAM周期的SAM周期.环闭式 σ 键转解.铁乙烯的合成方法σ-债券转化论 σ-债券转化论

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Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
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