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Entropy Change in Reversible Processes01:10

Entropy Change in Reversible Processes

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In the Carnot engine, which achieves the maximum efficiency between two reservoirs of fixed temperatures, the total change in entropy is zero. The observation can be generalized by considering any reversible cyclic process consisting of many Carnot cycles. Thus, it can be stated that the total entropy change of any ideal reversible cycle is zero.
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
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Entropy02:39

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Salt particles that have dissolved in water never spontaneously come back together in solution to reform solid particles. Moreover, a gas that has expanded in a vacuum remains dispersed and never spontaneously reassembles. The unidirectional nature of these phenomena is the result of a thermodynamic state function called entropy (S). Entropy is the measure of the extent to which the energy is dispersed throughout a system, or in other words, it is proportional to the degree of disorder of a...
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Entropy and the Second Law of Thermodynamics01:20

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The second law of thermodynamics can be stated quantitatively using the concept of entropy. Entropy is the measure of disorder of the system.
The relation  between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
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The Second Law of Thermodynamics01:14

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In the quest to identify a property that may reliably predict the spontaneity of a process, a promising candidate has been identified: entropy. Scientists refer to the measure of randomness or disorder within a system as entropy. High entropy means high disorder and low energy. To better understand entropy, think of a student’s bedroom. If no energy or work were put into it, the room would quickly become messy. It would exist in a very disordered state, one of high entropy. Energy must be...
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Probability in Statistics01:14

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Probability is the likelihood of an event occurring. The term event is defined as a collection of results of a procedure. An event is a simple event when an outcome cannot be divided into simpler parts.
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Updated: May 25, 2025

A Psychophysics Paradigm for the Collection and Analysis of Similarity Judgments
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热概率和上下文状态

Benjamin Schumacher1, Michael D Westmoreland2

  • 1Department of Physics, Kenyon College, Gambier, OH 43022, USA.

Entropy (Basel, Switzerland)
|February 26, 2025
PubMed
概括
此摘要是机器生成的。

这项研究将的概率扩展到一般的集合,将自由能量与信息删除和通用工作联系起来. 它建立在先前的公理信息热力学研究的基础上.

关键词:
这是麦克斯韦尔的恶魔.原理性的热力学.进入的过程中,有关信息信息信息信息信息信息.可能性概率概率概率.

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科学领域:

  • 物理 物理学 物理
  • 信息理论 信息理论
  • 热力学是一种热力学.

背景情况:

  • 之前的工作建立了信息热力学的公理系统.
  • 导出了一个包含热力学和信息组件的函数.
  • 对于统一的状态集合,获得了的概率分布.

研究的目的:

  • 为了将热概率的概念推广到超出统一的集合之外.
  • 为了更广泛的适用性,引入储库和上下文状态.
  • 建立自由能源,信息删除和通用工作之间的联系.

主要方法:

  • 增加状态与储库和上下文状态.
  • 将衍生的函数扩展到更一般的集合.
  • 发展一个抽象的自由能源概念.

主要成果:

  • 制定了一个通用的值概率分布.
  • 建立了自由能源的抽象概念.
  • 证明了自由能源,信息删除和通用工作之间的关系.

结论:

  • 一般化热概率框架为信息热力学提供了更全面的理解.
  • 这些发现将信息和热力学的基本概念联系起来.
  • 这项工作为探索信息删除和复杂系统中的通用工作开辟了道路.