相关实验视频
Updated: May 25, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
在近中性气电池中促进氧化物化学的光触媒双层阴极
Ruiya Wang1, Mingze Gao1, Guochao Zhao1
1College of Energy Material and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.
Journal of the American Chemical Society
|February 26, 2025
概括
可充电的空气电池通过使用新型的双层阴极实现更高的效率. 这种设计显著降低了电压歇斯底里,提高了储能应用的性能.
科学领域:
- 电化学
- 材料科学
- 能量储存
背景情况:
- 可充电的空气电池 (ZAB) 提供高能量密度和低成本,但由于阴极中氧气反应缓慢而遭受大电压歇斯底里.
- 避免使用现有的金属/金属氧化物催化剂,以防止电解质pH因水相关的副作用而被破坏.
研究的目的:
- 为近中性ZAB开发一种新的双层阴极,以克服缓慢的氧化转换和减少电压歇斯底里.
- 在不损害电解质完整性的情况下提高ZAB的能效和稳定性.
主要方法:
- 采用外部光催化剂 (Au@WO3) 和内部碳纳米管 (CNT) 层的双层阴极的制造.
- 使用光来激活光催化剂以进行电荷分离和转移到电催化剂.
- 在充电和放电周期下测试修改后的ZAB的性能.
主要成果:
- 双层阴极显著降低了电压歇斯底里,从> 600 mV降至< 150 mV.
- 在0.1 mA cm-2的电流密度下,ZAB表现出高稳定性.
- 用光催化剂增强的电荷转移有效降低了O2/ZnO2转换的过量潜力.
结论:
- 拟议的双层阴极设计成功地减轻了近中性ZAB的电压歇斯底里.
- 这种方法通过协同利用光催化和电催化来提高能源效率和稳定性.
- 这种策略避免了电解质pH破坏,为实用,高性能ZAB铺平了道路.
相关概念视频
Standard Electrode Potentials
43.2K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
43.2K
Batteries and Fuel Cells
26.9K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.9K
Electrodeposition
561
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
561
Voltaic/Galvanic Cells
56.3K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.3K
Electrolysis
25.9K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.9K
Concentration Cells
22.1K
A concentration cell is a type of a voltaic cell constructed by connecting two almost identical half-cells, both based on the same half-reaction and using the same electrode, differing only in the concentration of one redox species. A concentration cell's potential, therefore, is determined only by the concentration difference of the particular redox species.
Consider the following voltaic cell:
Consider the following voltaic cell:
22.1K

