一种弱酸性和还原性深度环氧溶剂,用于从已耗尽的离子电池中单步有效地分离Li和Co
Ronghao Liu1, Jun Li1, Ying Yue2
1Key Laboratory for Special Functional Aggregate Materials of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China.
Waste management (New York, N.Y.)
|February 26, 2025
概括
一种新型的深溶性溶剂使离子电池的高效单步回收成为可能,在保护环境的同时回收有价值的和资源.
科学领域:
- * 材料科学 材料科学
- * 绿色化学 绿色化学
- * 水电金术 (Hydrometallurgy) 是一种金术.
背景情况:
- *对离子电池的需求不断增长,使全球金属资源受到压力.
- *当前的回收方法可能是能源密集型和对环境有影响的.
- *需要可持续和高效的方法来回收和等关键金属.
研究的目的:
- * 开发一种绿色和成本效益高的深溶解剂 (DES),用于一级离子电池回收.
- *使用特定的DES配方研究和分离的机制.
- * 评估拟议的回收过程的效率和可持续性.
主要方法:
- * 制备一种弱酸性和还原性DES (乳酸:甘油酸 = 1:1).
- * DES的应用用于单步液和从使用过的离子电池中分离和.
- *使用分子动力学,FT-IR,1H NMR,UV-vis和XPS来描述DES特性和浸出机制.
- *使用收缩核心模型分析出水动力学.
- *循环漏实验以确定DES和负载.
主要成果:
- * 在最佳条件下 (6小时,100°C,L/S=10,MS=1:1) 达到超过99.5%的浸出效率.
- *的泄率主要由界面化学反应动力学决定.
- * 由于DES中的协同效应,可以在没有额外的剂量的情况下有效地沉.
- * 在循环水后,的最大DES和负荷达到5.18mg/g.
- *回收的产品包括Li2CO3和Co3O4.
结论:
- *开发的DES为回收离子电池提供了一种高效,低成本和环保的方法.
- * 这一单步过程简化了金属回收,减少了对危险化学品的依赖.
- * 该研究提供了一种可持续的战略,用于从废弃的离子电池中回收资源.
相关概念视频
Extraction: Advanced Methods
400
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
400
Electrodeposition
561
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
561
Capillary Electrophoresis: Applications
316
Capillary electrophoretic separations offer various modes, each with unique applications. These modes include capillary zone electrophoresis, capillary gel electrophoresis, capillary array electrophoresis, capillary isoelectric focusing, capillary isotachophoresis, micellar electrokinetic chromatography, and capillary electrochromatography.
Capillary zone electrophoresis (CZE) separates ionic components based on their electrophoretic mobility. It has been used to separate proteins, amino acids,...
Capillary zone electrophoresis (CZE) separates ionic components based on their electrophoretic mobility. It has been used to separate proteins, amino acids,...
316
Precipitation and Co-precipitation
1.6K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.6K
Ion Exchange
526
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
526
Sample Preparation for Analysis: Advanced Techniques
289
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
289


