通过双重交叉链接的多糖网络进行增强的石油回收,以获得更高的风力学和流量效率
Zhirong Zhang1, Linghui Sun1, Feiyu Chen1
1Chinese Academy of Sciences University, Beijing 101408, China; State Key Laboratory of Enhanced Oil Recovery, China Petroleum Exploration and Development Research Institute, Beijing 100083, China.
International journal of biological macromolecules
|February 26, 2025
概括
这项研究引入了一种新的双网络策略,使用韦兰和功能化聚烯胺来增强聚合物泛滥的石油回收. 新的生物聚合物系统显示出改进的质性质,并在各种储条件下显著提高了石油回收率.
科学领域:
- 聚合物化学 聚合物化学
- 增强石油回收的方法
- 材料科学 材料科学 材料科学
背景情况:
- 韦兰在恶劣的水库开发中被使用,因为它的加厚能力和耐温度和盐的耐受性.
- 然而,韦兰的刚性螺旋形状导致了较差的质性质,限制了其可注射性和微观位移效率.
研究的目的:
- 改进韦兰的分子构造和质性质,以提高油脂回收.
- 开发一种利用超分子相互作用的双重网络策略.
主要方法:
- 合成的β-cyclopodextrin功能化聚烯胺 (HPAM-CD) 和阿达曼坦修饰的韦兰 (WL-AD).
- 通过超分子相互作用创建了一个双网络交联系统 (WL-AD&HPAM-CD).
- 通过循环二元化,原子力显微镜和扫描电子显微镜评估了使用光学和形状变化的光学特性.
主要成果:
- 由于多种非共价相互作用,WL-AD&HPAM-CD系统表现出优异的质性质.
- 双网络结构在恶劣条件下提高了生物聚合物的弹性和形状稳定性.
- 与维兰和移植维兰相比,石油回收增加了4.99%和11.5%,在200mD核心中.
- 在低透度储 (10-50mD) 中,WL-AD&HPAM-CD 提高了石油回收率12.17-17.16%.
结论:
- 双重网络战略显著提高了韦兰的性能,提高了石油回收的效率.
- WL-AD&HPAM-CD提供了更好的注射性和位移效率,特别是在低透性的水库中.
- 这种方法为在石油工业中开发和应用生物聚合物提供了新的研究方向.
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