来自碳化渣和飞灰的微球地质聚合物的制备和吸附特性
Yinnian Liao1, Xiaoqing Ma2,3, Jinchi Zou2
1School of Life Sciences, Zhuhai College of Science and Technology, Zhuhai, 519041, China.
Scientific reports
|February 27, 2025
概括
由工业副产品制成的多孔微球地质聚合物有效地从水中去除铜 (II). 这种可持续材料具有很高的吸附能力和重金属修复的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 工业副产品如飞灰和碳化渣是丰富的.
- 开发有效的吸附剂来去除重金属对于环境保护至关重要.
- 将工业废物价值化为功能性材料解决了可持续性问题.
研究的目的:
- 用飞灰和碳化渣来制备多孔微球地质聚合物.
- 研究该地质聚合物在从水溶液中去除铜 (II) 的效率.
- 探索重金属吸附的工业副产品的潜力.
主要方法:
- 使用悬浮固化技术合成多孔微球地质聚合物.
- 过氧化和二硫酸盐被用作发泡剂.
- 进行了批量吸附实验,以确定不同条件下的铜 (II) 去除效率.
主要成果:
- 合成的地质聚合物具有63.46 m2·g-1.1的特定表面积.
- 在pH 5下发现了最佳的吸附条件,达到118.48mg·g-1.1的容量.
- 吸附过程遵循伪第一阶动力学和兰木尔异热模型,表明吸附和化学吸附机制.
结论:
- 来自工业副产品的多孔微球地质聚合物在Cu (II) 清除方面表现出色.
- 该材料具有较高的再生率 (83.20%) 和相比同类产品的优越吸附能力.
- 这项研究提供了一种新的方法,用于在环境修复中巧妙地利用工业废物.
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