相关实验视频

Updated: May 25, 2025

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines

Published on: January 3, 2018

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芳香的米斯洛 - 布拉弗曼 - 埃文斯阿里硫氧化物重新排列

Xinping Zhang1, Jiliang Li1, Madeline E Rotella2

  • 1Research Center for Chemical Biology and Omics Analysis, Department of Chemistry, Southern University of Science and Technology, 1088 Xueyuan Blvd., Shenzhen, Guangdong 518055, P.R. China.

JACS Au
|February 28, 2025
PubMed
概括

这项研究引入了一种新型的可爱芳香的Mislow-Braverman-Evans重排,使得从硫酸酸中合成醇. 这扩大了重新排列的范围,以创建多样化的酒精结构.

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Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine11:04

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

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Nucleophilic substitution in aromatic compounds is feasible in substrates bearing strong electron-withdrawing substituents positioned ortho or para to the leaving group. The reaction proceeds via two steps: the addition of the nucleophile and the elimination of the leaving group.
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