在--阴极材料中的Cu杂质的定量电化学分析方法
Woo Yeoul Shim1, Sangwoo Kim2, JungHye Won2
1Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea.
JACS Au
|February 28, 2025
概括
准确量化-- (NCM) 阴极中的残余铜 (Cu) 对电池性能至关重要. 使用Rh薄膜电极的电化学方法为NCM材料的微量Cu分析提供了灵敏而高效的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 分析化学 分析化学
背景情况:
- 离子电池 (LIB) 是重要的能量存储设备,由于其高能量密度和稳定性,-- (NCM) 阴极被广泛使用.
- 在NCM阴极中的铜 (Cu) 污染可以改善离子传输,但也会导致内部短路,需要精确的量化.
- 由于矩阵效应和操作挑战,传统的方法,如感应合等离子体,在NCM中难以准确的微量Cu量化.
研究的目的:
- 开发一种灵敏而准确的电化学方法,用于量化-- (NCM) 阴极材料中的微量铜 (Cu).
- 克服传统分析技术在NCM中确定残留Cu杂质方面的局限性.
- 为实验室和工业应用提供NCM阴极中Cu杂质评估的标准化指南.
主要方法:
- 利用电化学技术,特别是循环电压测量和电化学石英晶体微平衡,在 (Rh) 薄膜电极 (TFE) 上研究铜低电位沉积 (UPD).
- 采用正方形波电压测量,以基于Cuupd的动力差异来敏感量化微量Cu.
- 通过电化学方法最大限度地减少矩阵效应,开发了一种简化样品预处理过程.
主要成果:
- 开发的电化学方法在微量Cu量化方面表现出高灵敏度,实现了13-450ppb的线性范围和3.9ppb的检测极限.
- 较低的2.54%的相对标准偏差表明该方法的可靠性和可重复性.
- 成功地将该方法应用于商业NCM产品,使用标准添加方法确定Cu含量在40-60ppb之间.
结论:
- 电化学方法,特别是使用Rh TFE,显著减少矩阵效应,并简化样本准备用于NCM中微量Cu分析.
- 拟议的方形波电压测量方法为NCM阴极中的Cu量化传统方法提供了灵敏,准确和高效的替代方案.
- 这项研究建立了一个标准化的分析指南,用于评估各种NCM阴极材料中的Cu杂质,有利于研究和工业.
更多相关视频
06:53Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
1.9K
09:18Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
Published on: June 21, 2017
11.4K
相关概念视频
Electrodeposition
560
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
560
Precipitation Gravimetry
4.7K
Precipitation gravimetry is based on converting an analyte into a sparingly soluble precipitate, which is separated by filtration and weighed. An ideal precipitate should be pure, insoluble, of known composition, and easily filtered from the reaction mixture.
In determining nickel by gravimetric analysis, a precipitant of ethanolic dimethylglyoxime is added to a hot nickel salt solution. This is quickly followed by the dropwise addition of dilute ammonia solution until precipitation occurs. A...
In determining nickel by gravimetric analysis, a precipitant of ethanolic dimethylglyoxime is added to a hot nickel salt solution. This is quickly followed by the dropwise addition of dilute ammonia solution until precipitation occurs. A...
4.7K
Electrogravimetric Analysis: Overview
181
Electrogravimetric analysis measures the weight of an analyte deposited electrolytically onto a suitable working electrode. This method involves applying a potential to a pre-weighed electrode submerged in a solution, which results in the desired substance being deposited through reduction at the cathode or oxidation at the anode. The electrode's weight is recorded after deposition, and the difference in weight gives the analyte's weight in the solution.
To test the completeness of the...
To test the completeness of the...
181
Controlled-Potential Coulometry: Electrolytic Methods
123
Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
The chosen potential...
The chosen potential...
123
Precipitation and Co-precipitation
1.6K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.6K
Voltammetry: Stripping Methods
160
Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used to determine trace amounts of analytes in solution. These methods involve applying a potential to an electrode and measuring the resulting current.
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
160
