通过二元表面活性剂在紧的碳酸盐核心样本中流体流动的物理机制的实验研究
Ayomikun Bello1, Anastasia Ivanova1, Alexander Rodionov1
1Center for Petroleum Science and Engineering, Skolkovo Institute of Science and Technology, Skolkovo Innovation Center, 11 Sikorskiy Street, Moscow 143026, Russia.
Heliyon
|March 3, 2025
概括
二元表面活性剂通过改善流体流动来增强碳酸盐岩中的石油回收. 兹维特里欧尼克-非欧尼克表面活性剂混合物显示出优异的油脂回收,在自发的浸泡试验中表现优于单独的表面活性剂.
科学领域:
- 石油工程是石油工程中的一个.
- 表面化学 表面化学
背景情况:
- 碳酸盐岩石具有复杂的表面电荷,阻碍了用于增强流体流动的传统单一表面活性剂应用.
- 二元表面活性剂系统为修改具有挑战性的水库中的石化物理机制提供了更有效的替代方案.
研究的目的:
- 调查二元表面活性剂系统在改变流体岩石相互作用方面的有效性.
- 为了比较二元表面活性剂的吸附,可湿性变化和自发浸泡性能,与碳酸盐形成中的单个表面活性剂进行比较.
主要方法:
- 在八个表面活性剂系统上进行了静态吸附试验.
- 使用接触角测量来评估可湿度的变化.
- 在核心样本上进行了自发浸泡试验,以评估石油回收效率.
主要成果:
- 无离子表面活性剂显著降低了离子-无离子 (53%) 和离子-无离子 (28%) 混合物的吸附.
- 二元表面活性剂系统在自发浸泡试验中显示出更高的石油回收效率.
- 采用zwitterionic-nonionic系统回收的初始油量为58%,而单独回收的油量为31% (zwitterionic) 和25% (nonionic).
结论:
- 二元表面活性剂系统显示出在碳酸盐储库中增强石油回收的巨大潜力.
- 兹维特-非表面活性剂混合物特别有效,表明通过修改的石质物理机制优化了流体流动.
- 这些发现对改善碳酸盐形成中的过机制有意义.
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