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Uncertainty in Measurement: Accuracy and Precision03:37

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Scientists typically make repeated measurements of a quantity to ensure the quality of their findings and to evaluate both the precision and the accuracy of their results. Measurements are said to be precise if they yield very similar results when repeated in the same manner. A measurement is considered accurate if it yields a result that is very close to the true or the accepted value. Precise values agree with each other; accurate values agree with a true value. 
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Accuracy, limits, and approximations are common in many fields, especially in engineering calculations. These concepts are imperative for ensuring that a given value is as close as possible to its true value.
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The resolution of a mass spectrometer depends on the efficiency of separating ions with different ion masses. The mass of an atom is approximated to the sum of the masses of protons and neutrons inside, considering the masses of protons and neutrons as equal. However, the masses of the proton (1.6726 × 10−24 g) and neutron (1.6749 × 10−24 g) are not truly equal. There is a minor error in the expression of atomic masses relative to the simplest atom of hydrogen. For...
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Rapid Amplification of cDNA Ends, or RACE, is one of the most effective methods to obtain a full-length cDNA from an mRNA sequence between a known internal region to the unknown sequence at the 5’ or 3’ end. The unknown region is cloned in the cDNA by a gene-specific primer that binds the known end, and a hybrid primer that attaches a predefined anchor sequence to the unknown end of the cDNA. The sequence in between is amplified by PCR with an anchor primer and a gene-specific...
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精确的C2H2 通过在同结构协调网络中的功能化进行吸附亲和度调制.

Jian-Wei Cao1, Tao Zhang1, Yu-Qi Liu1

  • 1Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi, 710072, China.

Small (Weinheim an der Bergstrasse, Germany)
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PubMed
概括
此摘要是机器生成的。

研究人员通过调整在配体中,精确控制了多孔材料中的孔腔化学. 这增强了乙 (C2H2) 吸附,对于理解材料相互作用至关重要.

关键词:
晶体工程公司 晶体工程气体分离器 气体分离器乙乙烯的使用方法微孔协调聚合物微孔协调聚合物

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科学领域:

  • 材料科学 材料科学 材料科学
  • 化学 化学 化学
  • 纳米技术纳米技术

背景情况:

  • 对孔腔化学的精确控制对于理解多孔材料吸附至关重要.
  • 在不改变毛孔大小/几何形状的情况下使毛孔化学功能化是一个重大挑战.

研究的目的:

  • 开发一种方法来使多孔材料的孔腔化学功能化,同时保持一致的孔腔大小和几何形状.
  • 为了研究不同孔极性的对稳定的多孔框架内的乙烯吸附的影响.

主要方法:

  • 利用NPU-1系列网络作为材料合成的平台.
  • 通过调节双层-胺联体中的分布,合成了一系列协调网络 (NPU-1-TPB/TPP/TPT).
  • 在现场使用红外光谱学来分析乙相互作用.

主要成果:

  • 实现了具有相同孔径但具有不同的极性质的协调网络.
  • 证明了乙 (C2H2) 吸附热量从 -28.3 到 -33.1 kJ mol-1.1 的增加.
  • 观察到增强的C2H2相互作用与功能化相关联的联结体的中心环.

结论:

  • 这项研究成功地展示了一种调整多孔材料中多孔极性的策略,而不会影响多孔结构.
  • 配体的功能化显著提高了乙烯吸附亲和力.
  • 现场光谱学为气体与物质相互作用的机制提供了宝贵的见解.