从Bi3+ 增强红色排放 敏感的Eu3+ 激活的BaLaGa3 O7 光用于固态照明应用
B Vasanthi1,2, N Gopakumar2, P S Anjana3
1Post Graduate Department of Physics, All Saints' College, University of Kerala, Trivandrum, Kerala, India, 695007.
Journal of fluorescence
|March 4, 2025
概括
用 (Bi3+) 和欧 (Eu3+) 合的新型陶体显示出强烈的红光发射. 这些材料具有出色的热稳定性和机械发光,使它们适合用于LED和应力传感器.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低.
背景情况:
- 宽带间隙陶光对于光电子应用至关重要.
- 已知欧 (Eu3+) 兴奋剂会产生红色的辐射.
- (Bi3+) 敏感化可以增强发光特性.
研究的目的:
- 为了合成和描述Bi3+敏感的BaLa0.95Ga3O7:0.05Eu3+陶.
- 研究它们的结构,光学和发光性质.
- 评估它们在LED和传感器应用中的潜力.
主要方法:
- 合成的传统固态反应方法.
- 用于结构分析的X射线衍射 (XRD).
- 场辐射扫描电子显微镜 (FESEM) 和能量分散式X射线光谱 (EDAX) 用于形态学和元素分析.
- 紫外线可见吸收,光发光 (PL),温度依赖的光发光 (TDPL) 和机械发光 (ML) 研究用于光学和发光特性.
主要成果:
- 合成的光体呈现单相四角形结构,由XRD证实.
- 观察到强烈的红色辐射具有高颜色纯度,适合红色LED.
- 经过优化后的光剂表现出极好的热稳定性 (在423K保持91%的强度) 和显著的机械发光.
- 在使用Bi3+和Eu3+进行兴奋剂后,没有观察到任何显著的结构变化.
结论:
- Bi3+-敏感的BaLaGa3O7:Eu3+陶是光电子设备的有希望的材料.
- 它们强烈的红色发射,热稳定性和机械发光特性使它们适合UV/近UVLED和转换白色LED (WLED).
- 机械发光表明了作为压力传感器的潜在应用.
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