相关实验视频

Updated: May 24, 2025

Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering
06:16

Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering

Published on: December 21, 2017

5.7K

使用PFG NMR扩散度测量,追踪定期移植的两聚合物的溶剂诱导的形状崩

Harshita Sardana1, B V N Phani Kumar2, S Ramakrishnan1

  • 1Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, 560012, India. raman@iisc.ac.in.

Soft matter
|March 5, 2025
PubMed
概括

在特定的溶剂组合下,定期移植的两性聚合物 (PGAP) 在溶液中崩. 这种链条崩,由NMR证实,取决于聚合物结构和水友-友平衡.

更多相关视频

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy10:37

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy

Published on: March 16, 2020

9.5K
Self-Assembly of Gamma-Modified Peptide Nucleic Acids into Complex Nanostructures in Organic Solvent Mixtures08:15

Self-Assembly of Gamma-Modified Peptide Nucleic Acids into Complex Nanostructures in Organic Solvent Mixtures

Published on: June 26, 2020

4.2K

相关概念视频

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution00:52

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution

At room temperature, the chair conformer of cyclohexane undergoes rapid ring flipping between two equivalent chair conformers at a rate of approximately 105 times per second. These two chair conformers are in equilibrium. The rapid ring flipping results in the interconversion of the axial proton to an equatorial proton and an equatorial to the axial proton. Such interconversions are too rapid and cannot be detected on the NMR timescale. Hence, the NMR spectrometer cannot distinguish between the...
796
¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR01:15

¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR

The axial and equatorial protons in cyclohexane can be distinguished by performing a variable-temperature NMR experiment. In this process, except for one proton, the remaining eleven protons are replaced by deuterium. The deuterium substitution avoids the possible peak splitting caused by the spin-spin coupling between the adjacent protons. The remaining proton flips between the axial and equatorial positions.
1.0K