作为一种优质的过氧单硫酸盐激活剂,用于增强双降解的N-化生物炭-Fe/Mn
Huiji Xiao1, Yun Wang1, Kewei Lv2
1School of Life Sciences, Key Laboratory of Jiangxi Province for Functional Biology and Pollution Control in Red Soil Regions, Jinggangshan University, Ji'an 343009, China.
Water research
|March 5, 2025
概括
一种新的Fe-Mn双金属催化剂在N-doped生物炭 (FM@NBC-8) 上使用过氧硫酸盐 (PMS) 快速降解像双甲 (BPA) 这样的新出现的污染物. 这种先进的氧化系统显示了废水处理的高效率和稳定性.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 新兴污染物 (ECs) 由于其持久性和低度,对废水处理构成重大挑战.
- 先进的氧化过程 (AOP) 对于从水中去除反抗性有机污染物至关重要.
- 开发有效的催化剂来激活像过氧化硫酸盐 (PMS) 这样的氧化剂是提高AOP性能的关键.
研究的目的:
- 开发一个强大的Fe-Mn双金属催化剂,支持N-doped生物炭 (FM@NBC-8) 用于PMS介导的AOPs.
- 为了研究FM@NBC-8对双A (BPA) 降解的催化效率,一个代表的EC.
- 阐明降解机制,评估开发的催化剂的稳定性和实际适用性.
主要方法:
- 合成N-化生物炭和Fe-Mn双金属催化剂 (FM@NBC-8). 在这种过程中,N-化生物炭和Fe-Mn双金属催化剂的合成.
- 使用FM@NBC-8/PMS系统评估BPA降解效率.
- 动力分析,表面积测量 (BET) 和催化中间体和活性氧物种 (ROS) 的表征.
- 在广泛的pH范围和干扰离子存在下评估催化剂稳定性.
主要成果:
- 通过使用FM@NBC-8/PMS系统,在5分钟内完成BPA的完整降解,并消除高TOC.
- 与原始生物炭和单金属化催化剂相比,FM@NBC-8催化剂的降解率显著更高 (高达143倍).
- 增强的特定表面积和加速的电子转移促进了有效的PMS激活,产生硫酸盐和基激素 (SO4−•,OH) 和单一氧 (1O2).
- 催化剂在广泛的pH值范围内 (3-10) 显示出出色的稳定性和有效性,以及对常见离子的抗性.
结论:
- 开发的FM@NBC-8催化剂对PMS激活非常有效,可以快速和完全降解BPA.
- Fe,Mn,N-doping和生物炭支持的协同效应有助于催化剂的卓越性能和稳定性.
- 这种基于双金属生物炭的催化剂显示出在绿色环境中对新出现的污染物进行补救的实际应用的巨大潜力.
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