相关实验视频
Updated: May 24, 2025

09:50
Electrochemically and Bioelectrochemically Induced Ammonium Recovery
Published on: January 22, 2015
12.7K
10,000小时稳定的间歇性性海水电解
Qihao Sha1, Shiyuan Wang1,2, Li Yan1
1State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing, People's Republic of China.
Nature
|March 5, 2025
概括
由于间歇性可再生能源, 直接海水电解为绿色生产具有挑战性. 阴极上的新酸盐被动化层防止了降解,在频繁的启动停止周期中实现了稳定的进化.
科学领域:
- 电化学
- 材料科学
- 可再生能源
背景情况:
- 海水电解是绿色生产的一个有前途的途径.
- 由于化离子,直接海水电解面临阳极腐蚀和竞争反应.
- 之前的研究集中在阳极稳定性上,不考虑间歇性操作下的阴极降解.
研究的目的:
- 在间歇性海水电解过程中调查阴极降解.
- 开发一种在波动条件下提高阴极稳定性和性能的策略.
- 通过可再生电力实现实际的海水分裂技术.
主要方法:
- 研究海水分裂阴极的动态演变和降解.
- 提出并实施了催化剂被动化层战略.
- 在NiCoP-Cr2O3阴极上使用现场形成的酸盐被动化.
主要成果:
- 在间歇性电解下确定了阴极降解机制.
- 证明酸盐被动化层保护活性部位免受氧化,并驱逐化离子.
- 在性海水中在0.5 A cm−2下实现稳定的运行,电压增加率低 (0.5% khr−1).
结论:
- 通过间歇性可再生能源进行稳定的海水电解,
- 酸盐被动化层有效地提高了阴极的耐用性和性能.
- 这一战略促进了海水切割技术的发展.
更多相关视频
相关概念视频
Electrolysis
25.9K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.9K
Electrodeposition
560
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
560
Titration of Polyprotic Base with a Strong Acid
733
The titration of a polyprotic base such as sodium carbonate with a strong acid such as hydrochloric acid results in two equivalence points on the titration curve. At the first equivalence point, the carbonate ions in the base are completely converted to bicarbonate ions. The second equivalence point corresponds to the complete conversion of bicarbonate ions to carbonic acid, which dissociates into carbon dioxide and water. The region before the first equivalence point corresponds to the...
733
Controlled-Potential Coulometry: Electrolytic Methods
123
Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
The chosen potential...
The chosen potential...
123
Controlled-Current Coulometry: Overview
148
Controlled current coulometry, also known as amperostatic coulometry, is a technique used in electrochemical analysis to measure the quantity of a substance through the controlled passage of current. It involves the application of a constant current to an electrochemical cell containing the analyte of interest. As the current flows through the cell, the analyte undergoes a redox reaction at the electrode surface, resulting in a charge transfer. By monitoring the time required for a certain...
148
Ion Exchange
520
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
520

