使用聚乙烯四甲酸盐 (PET) 添加剂作为修饰剂的再生青路面的风学和化学特性
Christiana Adebola Odubela1,2, Haryati Yaacob3, Muhammad Naqiuddin Bin Mohd Warid3
1Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Malaysia. adebola@graduate.utm.my.
概括
本研究探讨使用再生PET瓶作为青中的添加剂. 聚乙烯添加剂增强了再生青路面 (RAP) 的性能,提高了道路建设的可持续性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 环境科学 环境科学
背景情况:
- 由于新材料的生产,道路建设面临高昂的成本和环境影响.
- 回收青路面 (RAP) 是一种潜在的可持续替代品,但其性能需要改进.
- 像PET瓶这样的废物材料为开发新的青改性剂提供了机会.
研究的目的:
- 研究用PET衍生添加剂修饰的再生青路面 (RAP) 的气质和化学特性.
- 为了评估聚合物改性 (PMB) 的有效性,在青混合物中使用PET添加剂.
- 评估PET添加剂在提高道路建筑材料性能和可持续性方面的潜力.
主要方法:
- 从废弃的PET瓶中合成PET衍生添加剂,使用与三乙烯二胺 (TETA) 的氨解方法.
- 通过将2%的PET添加剂添加到原始 (VB) 中,制造出聚合物改性 (PMB).
- 评估含有PMB和RAP青 (RB) 的青混合物的性能,通过学和化学分析.
主要成果:
- 聚乙烯添加剂改善了RAP青 (RB) 的脆性,提高了其性能.
- 修改后的青在高温下表现出很高的抗变形能力.
- 化学分析证实,PET添加剂不会改变青粘合剂的功能组.
- 对聚合物改性 (PMB) 观察到减少质量损失,表明稳定性得到改善.
结论:
- 聚乙烯 (PET) 添加剂有效地提高了青混合物的质量和性能.
- 在道路建设中使用PET添加剂有助于改善材料性能和可持续性.
- 回收PET为修改青粘合剂和减少道路建设的环境足迹提供了可行的解决方案.
相关概念视频
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Polymer Classification: Crystallinity
2.7K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.7K
Polymer Classification: Architecture
2.6K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.6K
Plasticizers
65
Water-reducers, or plasticizers, are chemical admixtures used in concrete to improve strength and workability. These additives reduce the water-cement ratio without compromising workability, lower the cement content while maintaining the same workability, or increase workability to assist concrete placement in inaccessible areas.
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
65
Retarders
61
Retarders are chemical admixtures designed to extend the setting time, which is especially useful when there is a delay in sequential concrete pours to prevent cold joints and to achieve a cohesive structure. Retarders, when used in appropriate amounts, can also enhance the architectural appearance of exposed aggregate finishes.
The function of retarders is to delay the setting of concrete, and this effect can be measured using a penetration test. The retardation process involves adding...
The function of retarders is to delay the setting of concrete, and this effect can be measured using a penetration test. The retardation process involves adding...
61
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)
1.9K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
1.9K


