透视酸通过非共价相互作用对大米粉特性的影响
Linlin Chen1, Xintong Li1, Wei Li1
1College of Food Engineering, Harbin University of Commerce, Harbin, China.
Journal of food science
|March 7, 2025
概括
了解酸如何与粉结合是开发新食品成分的关键. 这项研究揭示了控制粉特性的三种结合模式,使得有针对性的设计能够为更健康的食品和更好的包装提供帮助.
科学领域:
- 食品科学与技术 食品科学与技术
- 材料科学 材料科学 材料科学
- 生物化学 生物化学
背景情况:
- 对结构依赖的酸 (PA) 结合机制的有限理解阻碍了基于粉的先进材料的开发.
- 酸对于修改粉性质至关重要,影响消化能力和热力学特性.
- 目前的粉修饰方法往往是经验性的,缺乏对功能结果的精确控制.
研究的目的:
- 研究16种具有不同结构的酸与粉的结合机制.
- 阐明酸结构,结合方式和由此产生的粉特性之间的关系.
- 建立针对特定应用的粉材料设计的基本原则.
主要方法:
- 采用了多种技术的方法,包括里埃变换红外光谱学,X射线衍射,学和分子对接.
- 研究了16种具有不同氧化模式和甲氧替代的酸.
- 分析了基于PA结合的粉晶度,热稳定性和可消化的变化.
主要成果:
- 确定了三种不同的结合方式:聚基化PA与粉素螺旋形成桥梁结构复合物,甲基化PA通过螺旋腔中的疏水相互作用结合,以及与无形区域相互作用的酸.
- 通过强烈的复杂化,多氧化PA增加了相对晶度 (18% - 22%),降低了消化能力 (31% - 35%).
- 甲基化PA增强了热稳定性而不会改变结晶性,而肉酸则形成无形网络.
结论:
- 酸架构决定了粉中的超分子组装路径,结合点选择决定了功能特异性.
- 这些知识使得针对糖尿病友好的食品 (控制消化能力) 和可生物降解包装 (增强性质) 的粉能够有针对性的设计.
- 为开发下一代PA粉功能食品和材料提供科学基础,超越经验方法.
更多相关视频
10:30A Generalized Method for Determining Free Soluble Phenolic Acid Composition and Antioxidant Capacity of Cereals and Legumes
Published on: June 10, 2022
6.7K
09:43Author Spotlight: Streamlining Rice Breeding with CRISPR/Cas for Obtaining Optimal Phenotypic and Agronomic Traits
Published on: January 3, 2025
2.1K
相关概念视频
Acidity and Basicity of Alcohols and Phenols
18.5K
Like water, alcohols are weak acids and bases. This is attributed to the polarization of the O–H bond making the hydrogen partially positive. Moreover, the electron pairs on the oxygen atom of alcohol make it both basic and nucleophilic. Protonation of an alcohol converts hydroxide, a poor leaving group, into water—a good one. The two acid–base equilibria corresponding to ethanol are depicted below.
18.5K
Noncovalent Attractions in Biomolecules
47.0K
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
47.0K
Physical Properties of Alcohols and Phenols
13.9K
Alcohols are organic compounds in which a hydroxy group is attached to a saturated carbon. Phenols are a class of alcohols containing a hydroxy group attached to an aromatic ring. The physical properties of the alcohols and phenols are influenced by hydrogen bonding due to the oxygen–hydrogen dipole in the hydroxy functional group and dispersion forces between alkyl or aryl regions of alcohol and phenol molecules.
Alcohols possess a higher boiling point than aliphatic hydrocarbons of...
Alcohols possess a higher boiling point than aliphatic hydrocarbons of...
13.9K
Acidity of Carboxylic Acids
6.7K
Carboxylic acids are the strongest organic acids. However, their acidic strength is much less than mineral acids like HCl. Carboxylic acids ionize in water and readily lose the hydroxyl proton to form a resonance-stabilized carboxylate ion.
6.7K
Physical Properties of Carboxylic Acids
4.6K
Carboxylic acids with lower molecular weight exhibit a sharp and unpleasant odor. They also have higher boiling and melting points than analogous compounds, such as aldehydes, ketones, and alcohols.
4.6K
Basicity of Aliphatic Amines
5.6K
Amines can behave as Brønsted–Lowry bases by accepting a proton from the acid to form corresponding conjugate acids. Due to a lone pair of nonbonding electrons, aliphatic amines can also act as Lewis bases by forming a covalent bond with an electrophile.
To measure the basicity of amines, two conventions are generally used. The first defines Kb as the basicity constant for the deprotonation reaction of water by the amine, as presented in Figure 1. Conventionally, lower Kb indicates...
To measure the basicity of amines, two conventions are generally used. The first defines Kb as the basicity constant for the deprotonation reaction of water by the amine, as presented in Figure 1. Conventionally, lower Kb indicates...
5.6K
