接口金属协调双功能PtCo用于实际的燃料电池
Zhongliang Huang1, Qi Xiao2, Tianyi Ding1
1State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Science advances
|March 7, 2025
概括
这项研究引入了一种新的-催化剂在锡--碳支上,显著改善了质子交换膜燃料电池 (PEMFC) 中的CO耐受性和氧减少反应 (ORR) 活性. 这一突破使燃料电池能够高效地使用CO污染的燃料.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- (Pt) 是质子交换膜燃料电池 (PEMFC) 中的一个关键催化剂.
- Pt催化剂对一氧化碳 (CO) 的耐受性较差,氧降解反应 (ORR) 动力学较慢,特别是受污染的H2.
- 这限制了随时可用的H2来源,如蓝色和灰色的使用.
研究的目的:
- 为PEMFCs开发一种具有增强CO耐受性和ORR活性的新型催化剂.
- 为了使CO污染的在燃料电池中直接利用.
- 为了提高PEMFCs的整体性能和耐用性.
主要方法:
- 采用了一个金属接口协调策略.
- 设计了一种双功能- (PtCo) 金属间催化剂.
- 催化剂与--碳 (Sn-N-C) 支器相结合,形成了 Pt-Sn-N 键.
主要成果:
- PtCo/Sn-N-C催化剂显著提高了ORR活性和CO耐受性.
- 燃料电池在100ppm的CO/H2.2中达到2.11W/cm2的峰值功率密度.
- 在100ppm的CO/H2-空气条件下观察到超过710小时的稳定运行.
结论:
- 开发的PtCo/Sn-N-C催化剂有效地克服了传统Pt催化剂的局限性.
- 这项创新验证了在PEMFC中使用CO污染的可行性.
- 这些发现为在能源汽车中具有成本效益的PEMFC应用铺平了道路.
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