稀释驱动的凝-溶-凝-溶转换是由表面活性剂小粒的顺序演变
Shuo Lu1, Yashuang Liu1, Jinfeng Dong2
1Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, PR China.
Nature communications
|March 8, 2025
概括
稀释驱动了芳香水/zwitterionic表面活性剂混合物的过渡. 类似虫的微粒 (WLMs) 通过各种阶段进行转化,使可调节性质的可切换粘度流体成为可能.
科学领域:
- 合体和表面科学科学
- 材料化学 材料化学
- 类风病学 类风病学 类风病学
背景情况:
- 芳香的水和双基表面活性剂在水溶液中形成复杂的状结构.
- 了解相位过渡对于开发高级功能流体至关重要.
研究的目的:
- 为了研究芳香水/基表面活性剂混合物中的稀释驱动的凝-溶液-凝-溶液过渡.
- 阐明这些系统的自组装机制和相位行为.
主要方法:
- 通过稀释对成分度的系统变化.
- 使用已确定的技术 (隐含) 进行细胞结构和相位过渡的表征.
主要成果:
- 埃鲁基二甲胺贝他因 (EAPB) 溶液经历了连续的相变化:虫状 (WLMs) 变成六边形液晶 (H1),高度缩的球形 (HCSMs) 和六边形密封相 (HCP) 在添加盐酸盐 (NaSal) 后.
- 进一步稀释反转了这个过程:HCP变成HCSM,WLM和球状小粒 (SM),证明了凝-溶液-凝-溶液的过渡.
- 一个涉及SM聚合和重组的缓慢运动过程形成了WLMs,造成了显著的加厚效应.
结论:
- 稀释是控制水和表面活性剂之间的竞争性自我分类和联合组装的关键因素.
- 这种控制有助于创建和应用具有可切换粘度的WLM流体.
相关概念视频
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Detergent Purification of Membrane Proteins
5.1K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.1K
Solubility
17.2K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.2K
Chemical and Solubility Equilibria
4.0K
The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place,...
4.0K
Solution Formation
31.0K
There is no one solvent that can dissolve every type of solute. Some substances that readily dissolve in a certain solvent might be insoluble in a different solvent. A simple way to predict which substances dissolve in which solvent is the phrase "like dissolves like". This means that polar substances, such as salt and sugar, dissolve in a polar substance like water. In contrast, non-polar substances are more soluble in non-polar solvents such as carbon tetrachloride.
This selective...
This selective...
31.0K
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
264
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
264


