轮胎的热解特性 在低温下
Emmanuel Awosu1, Yuka Hirano1, Shogo Kumagai1,2
1Graduate School of Environmental Studies, Tohoku University, 6-6-07 Aoba, Aramaki-aza, Aoba-ku, Sendai, Miyagi 980-8579, Japan.
ACS omega
|March 10, 2025
概括
使用过的轮胎的低温热解有效地回收液体并保留碳黑. 这种方法降低了的分子量,并改善了异烯回收,提供了可持续的回收解决方案.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 传统的轮胎热解面临的挑战是低的异烯回收,碳黑损伤和焦炭形成.
- 基于天然 (聚二烯) 的轮胎需要先进的回收方法来克服这些限制.
研究的目的:
- 为了研究硫化,含碳黑的轮胎的低温热解的特点.
- 评估有价值的化学品,特别是异烯的回收,以及回收的碳黑的质量.
主要方法:
- 轮胎的低温热解在不同的温度和持续时间进行.
- 进行了回收液体,分子量减少和异烯骨架保留的分析.
- 对回收的黑碳进行了残留基质的表征.
主要成果:
- 在282°C温度下1小时内,达到76.7%的最大液体回收率.
- 的分子重量从34万MW下降到大约20,000MW.
- 在267°C时观察到高的异烯骨保留率 (83%),碳黑上的矩阵在320°C以上几乎被消除.
结论:
- 低温热解是一种可行的预处理方法,用于轮胎回收.
- 这一过程使得碳黑能够高效地回收,而热损伤最小.
- 降低分子量和改善异烯回收是这种方法的关键好处.
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