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Updated: May 23, 2025

Protocol for Measuring the Thermal Properties of a Supercooled Synthetic Sand-water-gas-methane Hydrate Sample
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Published on: March 21, 2016

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简化的气体状态方程在和和同热状态

Xiuyun Cui1, Longyang Liu2, Mingkun Jiang2

  • 1School of Chemistry and Chemical Engineering, Huangshan University, Xihai Rd. 39#, Tunxi, Huangshan 245041, Anhui Province, China.

ACS omega
|March 10, 2025
PubMed
概括

本研究引入了一个简化的气态方程 (EOS),使用新的热力学常数P*c,验证亨利定律,并显示气液系统的潜力. 经过修改的EOS提供了对各种压力和温度的气体行为的洞察.

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Spin Saturation Transfer Difference NMR SSTD NMR: A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes11:44

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Ideal Gas Equation01:17

Ideal Gas Equation

The ideal gas equation is an equation of state that relates the state variables pressure, volume, temperature, and the number of moles of a hypothetical gas. This equation is a combination of four empirical laws, namely Boyle’s Law, Charles’s Law, Avogadro’s Law, and Gay-Lussac’s Law. When the proportionalities of the above four empirical laws are combined, it results in a single proportionality constant known as the universal gas constant.
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pV-Diagrams01:18

pV-Diagrams

The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
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Van der Waals Equation01:10

Van der Waals Equation

The ideal gas law is an approximation that works well at high temperatures and low pressures. The van der Waals equation of state (named after the Dutch physicist Johannes van der Waals, 1837−1923) improves it by considering two factors.
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
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Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation04:01

Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation

Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws. 
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Gas Laws: Boyle's, Gay-Lussac, Charles', Avogadro's, and Ideal Gas Law03:19

Gas Laws: Boyle's, Gay-Lussac, Charles', Avogadro's, and Ideal Gas Law

Through experiments, scientists established the mathematical relationships between pairs of variables, such as pressure and temperature, pressure and volume, volume and temperature, and volume and moles, that hold for an ideal gas.
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Isothermal Processes01:21

Isothermal Processes

A thermodynamic process that occurs at constant temperature is called an isothermal process. Heat slowly flows into the system or out of the system to maintain thermal equilibrium. Processes involving phase changes like water evaporation into steam or freezing water into ice at a constant temperature are examples of Isothermal Processes.
An ideal gas can also undergo isothermal expansion or compression.
For example, consider 1 mole of an ideal gas inside an isolated cylinder at initial volume V...
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