精确控制结晶动力学,通过结合核剂和可塑剂,达到20.1%的效率有机太阳能电池
Bo Cheng1, Xinxin Xia1, Sixuan Cheng1
1National Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, 250100, China.
Advanced materials (Deerfield Beach, Fla.)
|March 11, 2025
概括
研究人员使用聚合物供体D18-Cl和小分子受体AITC开发了一种新的四元策略,以控制有机太阳能电池 (OSC) 形态. 这种方法精确调节结晶,显著提高设备性能,并实现20.1%的功率转换效率.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 可控制的活性层形态对于提高有机太阳能电池 (OSC) 性能至关重要.
- 现有的策略往往在对形态进化的精确控制方面扎.
- 开发先进的形态控制方法是实现更高功率转换效率的关键.
研究的目的:
- 采用四级策略,精确调制OSC中的结晶动力学和活性层形态.
- 研究聚合物供体D18-Cl和小分子受体AITC对形态学的协同作用.
- 为了实现优化的3D形态,以提高设备性能和减少能源损耗.
主要方法:
- 将聚合物供体D18-Cl和小分子受体AITC纳入主体D18:N3系统.
- 在膜形成期间进行现场光谱测量,以监测结晶动力学和形态演变.
- 分析双客对捐赠者/接受者的聚合和混合的影响.
主要成果:
- D18-Cl作为核子,促进了D18的聚合和供体/受体混合.
- AITC充当了增塑剂,反对N3聚合和混合动力学.
- 结合的效果导致了对纤维状网络的协同控制,多长度尺度形态和垂直相分布,从而实现了优化的3D形态.
结论:
- 四元策略通过双客的相互补偿效应来实现对活性层形态的协同控制.
- 优化的形态增强了刺激子解离,电荷转移,抑制了重组,并减少了能量损失.
- 单节OSC的功率转换效率达到了20.1%,证明了对高性能设备的有效方法.
相关概念视频
Recrystallization: Solid–Solution Equilibria
1.0K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.0K
Crystal Growth: Principles of Crystallization
1.5K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
1.5K
Polymer Classification: Crystallinity
2.7K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.7K
Ziegler–Natta Chain-Growth Polymerization: Overview
3.2K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
3.2K


