基于N-氧化物Zwitterionic的防松散纳米过膜具有优越的水透性和有效的染料/盐分离
Ziming Wang1, Shideng Yuan1, Dong Wang1
1Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong 266237, P. R. China.
Environmental science & technology
|March 11, 2025
概括
一种新的三甲基胺N-氧化物基聚乙烯胺 (TPEI) 松散纳米过 (LNF) 膜提供优越的水透性和染料排斥. 这种高性能膜在废水处理中表现出极好的防腐性能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 松散的纳米过膜 (LNF) 对于分离有机染料和无机盐至关重要.
- 开发具有高透性和选择性的膜对于高效的废水处理至关重要.
- 现有的膜往往面临着污染和有限的分离能力的挑战.
研究的目的:
- 使用三甲基胺N氧化物基聚乙烯胺 (TPEI) 制造一种新的聚胺LNF膜.
- 评估分离性能,包括水透率和染料和盐的排斥.
- 为了评估抗污染性质,并与商业膜进行性能比较.
主要方法:
- TPEI和三聚化 (TMC) 的界面聚合 (IP) 形成一个聚胺层.
- 膜形态,结构和分离性能的表征.
- 测试染料和无机盐的排斥,水的透性,和防行为.
主要成果:
- 该NF-TPEI膜实现了高的水透率 (213.0 L m-2 h-1 bar-1).
- 刚果红 (99.8%),库马西蓝R250 (99.5%) 和埃文斯蓝 (99.9%) 的异常拒绝率.
- 低排斥无机盐 (<7.0%) 和优秀的防性能 (96.0-98.1%的回收率).
结论:
- 这种基于TPEI的新型LNF膜表现出卓越的分离性能和防腐性.
- 这种膜为废水处理中有效去除有机污染物提供了一个有希望的解决方案.
- 这些发现为环境应用中先进的LNF膜提供了新的可能性.
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