新出现的微污染物的吸附在轮胎磨损颗粒上
Dimitrios Vlachos1, Dimitra Voutsa1
1Environmental Pollution Control Laboratory, School of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54 124, Greece.
The Science of the total environment
|March 11, 2025
概括
轮胎磨损颗粒 (TWP) 在水生环境中吸收诸如双A (BPA) 和黄 (BT) 等微污染物. 老化过程和盐度会影响这种吸附,TWP显示出与聚乙烯微塑料相似的风险.
科学领域:
- 环境科学 环境科学
- 环境化学环境化学
- 材料科学 材料科学 材料科学
背景情况:
- 轮胎磨损颗粒 (TWP) 是水生生态系统中微塑料 (MP) 的重要来源.
- 新兴的微污染物如双A (BPA) 和1H-二 (BT) 经常在水体中检测到.
- 了解MP的吸附行为对于评估其环境风险至关重要.
研究的目的:
- 为了研究TWP对BPA和BT的吸附行为.
- 评估衰老过程 (光衰老,化学衰老,生物衰老) 对TWP吸收的影响.
- 为了比较TWP与聚乙烯 (PE) 的吸收能力,并评估pH和盐度等环境因素的影响.
主要方法:
- 进行了批量吸附实验,以确定吸附动力学和热力学平衡.
- 系统地研究了pH值,离子强度 (盐度) 和衰老对TWP吸附的影响.
- 还进行了吸附实验,使用聚乙烯 (PE) 作为参考材料进行比较.
主要成果:
- TWP显示BPA的吸附亲和力比BT的吸附亲和力高.
- TWP的光衰老显著增强了BPA和BT的吸附.
- 化学和生物老化减少了BPA的吸附,而盐度增加对这两种化合物的吸附产生了负面影响.
- TWP的吸附行为与PE相似,表明它具有类似的潜力作为这些微污染物的载体.
结论:
- 在水生环境中,TWP有效吸收新出现的微污染物BPA和BT.
- 老化过程和盐度等环境条件显著改变了TWP的吸收能力.
- TWP和PE的可比吸附行为表明,TWP与微污染物的载体具有类似的环境风险.
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