相关实验视频
Updated: May 22, 2025

09:26
Synthesis and Characterization of Supramolecular Colloids
Published on: April 22, 2016
9.7K
在合体流体中调更高阶结构
Xiaoyue Wu1, Katherine Skipper2, Yushi Yang2
1School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK.
Soft matter
|March 12, 2025
概括
由于双极相互作用,合粒子在电场下形成"弦流体"结构. 实验和模拟证实了这些结构,揭示了粒子自我组装动态的洞察力.
科学领域:
- 体科学 体科学 体科学
- 软物质物理学 软物质物理学
- 计算物理 计算物理
背景情况:
- 在交流电场下的诱导二极相互作用驱动下,体粒子自组合成多样化的结构.
- 在低体积分数下,这些系统在硬球状状态 (无场) 和"弦流体" (场应用) 之间进行过渡.
研究的目的:
- 研究状系统中"弦流体"状态的出现.
- 使用实验和模拟方法分析结构性质.
- 描述更高阶的相关性和最小能量集群.
主要方法:
- 采用了粒子解析实验和计算机模拟.
- 结构分析利用了双体和更高阶的相关函数.
- 基于双极-列纳德-斯系统的最小能量集群的多体方法被用来探测更高阶结构.
主要成果:
- 在两体相关性水平上,实验和模拟数据之间发现了良好的一致性.
- 对于更高层次的相关性,观察到合理的协议,对于三体相关性,在更高的场强度上增加了差异.
- 在更高的电场强度下,在实验和模拟中,最小能量集群 (大小为8 ≤ m ≤ 12) 主导了集群群体.
结论:
- 该研究成功地描述了状系统中的"弦流体"状态.
- 实验和模拟结果显示出很好的一致性,特别是在两体水平.
- 高阶结构分析,包括最小能量集群,为现场诱导的自我组装提供了更深入的见解.
相关概念视频
Colloidal precipitates
474
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
474
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Coagulation
256
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
256
Colloids and Suspensions
1.6K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.6K
Solubility
17.2K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.2K
Precipitate Formation and Particle Size Control
656
In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
656

