关于水性聚氨改性氧化物的机械和热性能及其在LDPE塑料中的应用的研究
Xianrong Yang1,2, Gaoxiang Du1,2, Huan Shuai1
1School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China.
Polymers
|March 13, 2025
概括
水性聚氨 (WPU) 有效地修改氧化 (ATH) 进行增强低密度聚乙烯 (LDPE) 复合材料. 这提高了分散性,机械强度和阻燃性,提供了具有成本效益的材料增强.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 复合材料 复合材料 复合材料
背景情况:
- 氧化 (ATH) 是聚合物的常见阻燃填充剂.
- 在聚合物矩阵中改善ATH分散和界面兼容性仍然是一个挑战.
- 低密度聚乙烯 (LDPE) 复合材料对于更广泛的应用需要增强的机械和热性能.
研究的目的:
- 通过使用水性聚氨 (WPU) 来研究氧化物 (ATH) 的修饰.
- 评估WPU修饰的ATH对LDPE复合材料的分散,机械性能和热性能的影响.
- 评估WPU修饰的ATH作为增强填充剂和阻燃剂的潜力.
主要方法:
- 使用优化湿工艺与WPU进行ATH粉末的修改.
- 修改效率使用SEM,XRD,FTIR,XPS和TGA进行了评估.
- 用修改ATH填充的LDPE复合材料被准备好,并对机械和热性能进行了表征.
主要成果:
- 修改WPU显著改善了ATH在有机阶段的分散,以及与LDPE的界面兼容性.
- 修改后的ATH增强了LDPE复合材料的机械性能,在3.0重量%的WPU下具有最佳性能.
- 含有高达60%ATH的复合材料表现出更好的阻燃性和耐火性.
结论:
- PU是ATH的有效修饰剂,增强其作为LDPE中的填充剂的性能.
- 修改为WPU的ATH为LDPE复合材料提供了增强和阻燃的双重好处.
- 这种方法提供了一个可行的策略,以提高LDPE复合材料的成本效益.
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