生物基和无溶剂的环氧玻璃基,基于具有高机械性能的动态胺基键
Lei Chen1, Na Ning1, Gang Zhou1
1Center for Civil Aviation Composites, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.
Polymers
|March 13, 2025
概括
这项研究引入了新的生物基环氧玻璃制品,使用动态胺基键,提供出色的机械性能和再加工能力. 这些可持续材料为传统热提供了可回收的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续化学 可持续化学
背景情况:
- 传统的环氧热是不可回收的,并且来自石油.
- 开发可持续的,可再加工的替代品至关重要.
研究的目的:
- 合成生物基环氧玻璃剂,具有动态的胺基键.
- 调查交叉连接密度和 imine 含量的影响.
- 评估热,机械和再加工性能.
主要方法:
- 无溶剂的一合成,使用瓦尼林衍生单体,DDS和BFDGE.
- 热性能,紫外线屏蔽,耐溶剂和机械强度的表征.
- 对再加工性和降解行为的评估.
主要成果:
- 实现了高抗拉强度 (109 MPa) 和模量 (6257 MPa).
- 证明了出色的热稳定性,紫外线屏蔽和耐溶剂.
- 具有良好的再加工能力 (>70%的回收) 和由酸引起的降解.
结论:
- 成功制备了高性能,生物基的环氧玻璃.
- 动态的胺基键可以实现回收和温和的降解.
- 为先进的耐热材料提供可持续和有效的途径.
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