基于低α-纤维素的膜
Igor Makarov1, Gulbarshin Shambilova2,3, Aigul Bukanova3
1A.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Prospect 29, 119991 Moscow, Russia.
Polymers
|March 13, 2025
概括
这项研究探讨了用于膜的纸纤维素,发现红素含量影响了强度和染料排斥等特性. 这些发现表明,有可能出现新的基于纤维素的材料.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 纤维素生产方法显著影响其α分数含量.
- 纸,不到90%的α分数,不同于溶解纤维素.
- 纤维素卫星不会阻碍缩的N-甲基摩尔福林-N-氧化物 (NMMO) 溶液.
研究的目的:
- 调查低α分数纤维素 (纸纤维素) 的线溶液.
- 检查这些溶液的形态特征和质行为.
- 探索滚动溶液的潜力,以创建纤维素膜.
主要方法:
- 使用X射线衍射,红外光谱,原子力显微镜 (AFM) 和扫描电子显微镜 (SEM).
- 分析了从纤维素纸中提取的膜的结构和形态.
- 评估了膜特性,包括强度,弹性模量,接触角度和染料排斥.
主要成果:
- 膜结晶度因杂质含量而异.
- 电影呈现出密集的纹理,没有真空孔.
- 漂白硬木硫酸纤维素产生了具有最高强度 (5.7 MPa) 和弹性模量 (6.4 GPa) 的膜.
- 较高的素含量与接触角度 (高达48°) 的增加以及对阳离子染料的更强的排斥有关.
结论:
- 纸纤维素可以加工成具有可控制性质的膜.
- 氨酸的存在对染料排斥中的膜性能产生了积极的影响.
- 该研究表明,在膜制造中利用低档纤维素的潜力.
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