聚四乙烯 (PTFE) 燃烧特性和有毒物质的形成在氧化器通过激光吸收断层扫描通过激光吸收断层扫描的交叉流
Isabelle C Sanders1, Katherine A Oberlander1, R Mitchell Spearrin1
1Department of Mechanical and Aerospace Engineering, University of California, Los Angeles (UCLA), Los Angeles, California, 90095.
概括
这项研究开发了一种用于耐火聚合物的新二维燃烧实验,使用激光诊断来测量燃烧特征和有毒物质的形成,帮助消防安全研究.
科学领域:
- 燃烧科学 燃烧科学
- 聚合物化学 聚合物化学
- 激光诊断 激光诊断 激光诊断
背景情况:
- 耐火聚合物带来了独特的燃烧挑战.
- 了解有毒物质的形成对于消防安全至关重要.
- 在现场测量需要先进的诊断.
研究的目的:
- 开发一种用于研究固体燃料聚合物燃烧的二维实验方法.
- 评估烧伤特征和有毒物质的形成.
- 为了使物种和温度在现场进行测量.
主要方法:
- 开发了一项2D固体燃料燃烧实验,采用强制对流式交叉流.
- 使用红外二极管和量子级联激光器进行物种 (HF,CO) 和温度测量.
- 应用激光吸收断层扫描 (LAT) 用阿贝尔倒置进行2D重建.
主要成果:
- 检查了聚四乙烯 (PTFE) 燃料附近的热化学流场结构.
- 从吸收过渡中推断的温度和摩尔分数.
- 产生了近表面反应层的2D图像.
结论:
- 开发的方法为聚合物燃烧提供了定量热化学数据.
- 使用现有模型进行模拟有助于阐明趋势并确定关键反应.
- 实验设置适用于验证反应式多物理模型,以改进消防安全预测.
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