在Sm2Mn1-xGa6-yGey中,由疾病和磁力驱动的结构变化
Roman A Khalaniya1, Andrei V Mironov1, Aleksandr Kulchu1
1Department of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, Moscow, 119991, Russian Federation.
概括
这项研究揭示了磁过渡附近的Sm2Mn1-xGa6-yGey化物中负热膨胀. 结构变化和缺陷驱动这些不寻常的扩张行为.
科学领域:
- 固态化学 固态化学
- 晶体学 晶体学是指结晶学.
- 材料科学 材料科学 材料科学
背景情况:
- Sm2Mn1-xGa6-yGey属于填充的AuCu3型化物家族.
- 这些化合物表现出复杂的晶体结构,具有独特物理性质的潜力.
研究的目的:
- 研究Sm2Mn1-xGa6-yGey的晶体结构.
- 分析其结构性质的温度依赖性,特别是热膨胀.
- 了解磁性转换和结构行为之间的关系.
主要方法:
- 高分辨率的单晶X射线衍射.
- 从180K到430K的可变温度研究.
主要成果:
- 该化合物结晶成一个立方F中心的结构,交替空和满Mn的八面体.
- 在磁相过渡附近观察到负热膨胀 (NTE) 的狭窄区域.
- 由于结构缺陷和放松,在375-400K之间发生了额外的结构转变.
结论:
- 磁性转换显著影响原子结构,导致负热膨胀.
- 结构缺陷在诱导纯粹结构性转型方面发挥着至关重要的作用.
- 这些化物中的磁性,结构和缺陷之间的相互作用是复杂的,需要进一步调查.
更多相关视频
09:06Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
Published on: March 24, 2019
8.0K
06:53Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
1.9K
相关概念视频
Atomic Nuclei: Nuclear Relaxation Processes
598
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis, the precessing magnetic moments are randomly oriented around the z-axis.
598
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Colors and Magnetism
11.4K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.4K
Diamagnetism
2.4K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.4K
Paramagnetism
2.5K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.5K
Atomic Nuclei: Magnetic Resonance
600
The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
600
