Ag-Ce0.9Gd0.1O2-δ-基于纳米复合材料薄膜空气电极用于低温固体氧化物电池
Ozden Celikbilek1,2, Matthew P Wells3, Judith L MacManus-Driscoll3
1Department of Materials, Imperial College London, Exhibition Road, London SW7 2AZ, U.K.
概括
研究人员开发了用于固体氧化物细胞 (SOCs) 的新型银氧化物 (Ag-CGO) 纳米复合材料薄膜. 这些薄膜在低温下提供高性能,大大减少了对贵金属的需求.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 控制材料接口对于在低温 (<700°C) 工作的高性能,耐用的固体氧化物电池 (SOC) 是关键.
- 纳米复合材料异构结构通过精确控制组成,厚度和表面化学,提供独特的接口特性.
研究的目的:
- 开发新的Ag-Ce0.9Gd0.1O2-δ (Ag-CGO) 纳米复合材料薄膜用于低温SOC电极.
- 评估这些薄膜的性能,作为替代传统散装银电极的选择.
主要方法:
- 使用单步脉冲激光沉积 (PLD) 工艺制造Ag-CGO纳米复合材料薄膜.
- 在伊特里亚稳定 (YSZ) 基板上生长密薄膜 (30和300 nm).
- 在对称的细胞配置中,区域特异性电阻 (ASR) 的表征.
主要成果:
- 成功制造了密集的Ag-CGO纳米复合材料薄膜.
- 300纳米厚的薄膜在480°C时实现了22.6 Ω cm2的ASR.
- 性能相当于微米厚的散装Ag电极,但含银量显著降低.
结论:
- Ag-CGO纳米复合材料薄膜是用于低温SOC的散装Ag电极的有希望的替代品,减少了贵金属的使用.
- PLD制造工艺适用于薄膜SOC制造,消除了沉积后化.
- 这些薄膜也可能在其他低温催化应用中具有潜力.
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