在CeO2,TiO2和ZrO2上的NiFe支持作为性介质中高效的氧进化反应催化剂
Neethu Kochukunnel Varghese1, Elina Mkrtchian2, Anshika Singh3
1Department of Chemistry and Industrial Chemistry, University of Genoa, 16146 Genoa, Italy.
概括
金属氧化物支上的铁纳米粒子在离子交换膜水电解中显示出高活性和稳定性,促进了绿色的生产.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 绿色化学 绿色化学
背景情况:
- 传统的水电解是昂贵和能源效率低下的,阻碍了绿色的采用.
- 阳离子交换膜 (AEM) 水电解利用过渡金属催化剂提供了一个具有成本效益和高效率的替代方案.
研究的目的:
- 为了研究-铁 (NiFe) 纳米颗粒在氧化金属支上的催化活性和稳定性,用于氧化演化反应 (OER).
- 评估这些催化剂在AEM电解器中的应用潜力.
主要方法:
- 在CeO2,TiO2和ZrO2基材上对具有不同Ni:Fe比率的NiFe纳米粒子进行电化学测试.
- 对氧气演化反应的超电位,塔菲尔斜率和电化学稳定性的评估.
主要成果:
- Ni90Fe10纳米粒子表现出最高的催化活性和稳定性在CeO2.
- 所有测试的金属氧化物支 (CeO2,TiO2,ZrO2) 在高电流密度下都表现出高活性和良好的性能.
- TiO2提供了卓越的稳定性,在高电流密度下具有与CeO2相比的超电位.
结论:
- 铁的添加显著增强了OER的纳米颗粒的催化活性.
- 金属氧化物支对于提高AEM水电解中的NiFe催化剂的稳定性和性能至关重要.
相关概念视频
Necrosis
3.8K
Necrosis is considered as an “accidental” or unexpected form of cell death that ends in cell lysis. The first noticeable mention of “necrosis” was in 1859 when Rudolf Virchow used this term to describe advanced tissue breakdown in his compilation titled “Cell Pathology”.
Morphological Manifestations of Necrosis
Necrotic cells show different types of morphological appearance depending on the type of tissue and infection. In coagulative necrosis, cells become...
Morphological Manifestations of Necrosis
Necrotic cells show different types of morphological appearance depending on the type of tissue and infection. In coagulative necrosis, cells become...
3.8K
Nociception
27.6K
Nociception—the ability to feel pain—is essential for an organism’s survival and overall well-being. Noxious stimuli such as piercing pain from a sharp object, heat from an open flame, or contact with corrosive chemicals are first detected by sensory receptors, called nociceptors, located on nerve endings. Nociceptors express ion channels that convert noxious stimuli into electrical signals. When these signals reach the brain via sensory neurons, they are perceived as pain.
27.6K
Nuclear Export
3.6K
The nucleus restricts several proteins within and allows others to pass. The restricted proteins possess a nuclear retention sequence or NRS, anchoring them to the nuclear lamins and preventing their transport to the cytosol. The non-restricted proteins, after their synthesis, are transported to their site of action, such as the cytosol or other organelles, with the help of nuclear export signals or NES.
NES are of three types- the canonical 10-residue long leucine-rich signal and other...
NES are of three types- the canonical 10-residue long leucine-rich signal and other...
3.6K
NF-κB-dependent Signaling Pathway
7.2K
The transcription factor NF-κB was discovered in 1986 in the lab of Nobel laureate Professor David Baltimore, for its interaction with the immunoglobulin light chain enhancer in B-cells. After more than three decades of study, it is now evident that NF-κB regulates the expression of over 100 genes. Most of these genes play an essential role in the innate and adaptive immune responses as well as the inflammatory responses of animals.
NF-κB-dependent Signaling Mechanism
The...
NF-κB-dependent Signaling Mechanism
The...
7.2K
The Nucleus
89.2K
The nucleus is a membrane-bound organelle that acts as a control center in a eukaryotic cell. It contains chromosomal DNA, which controls gene expression and precisely regulates the production of proteins within the cell. In contrast, the DNA inside the mitochondria and chloroplast only carries out functions that are specific to those organelles.
Arrangement of DNA within Nucleus
The regulation of gene expression inside the nucleus is dependent on many factors, including the DNA structure. The...
Arrangement of DNA within Nucleus
The regulation of gene expression inside the nucleus is dependent on many factors, including the DNA structure. The...
89.2K
Nucleophiles
13.0K
The word “nucleophile” has a Greek root and translates to nucleus-loving. Nucleophiles are either negatively charged or neutral species with a pair of electrons in a high-energy occupied molecular orbital (HOMO). As these species tend to donate electron pairs, nucleophiles are considered Lewis bases as well. Negatively charged species, like OH−, Cl−, or HS−, with one or several pairs of electrons, are typically nucleophiles. Similarly, neutral species such as...
13.0K


