对凝聚性颗粒颗粒颗粒的聚合物的悬挂滴试验
Yasaman Heshmatzadeh1, Jean-Christophe Ono-Dit-Biot1, Kari Dalnoki-Veress1,2
1Department of Physics & Astronomy, McMaster University, Hamilton, ON, L8S 4L8, Canada. dalnoki@mcmaster.ca.
Soft matter
|March 14, 2025
概括
这项研究探讨了颗粒状集群脱落,发现集群体积取决于孔径大小和粒子凝聚力,而不是滴滴大小. 颗粒状集群因粒子重排的约束而不同于液滴.
科学领域:
- 软物质物理学 软物质物理学
- 颗粒物质科学 颗粒物质科学
- 接口现象 接口现象
背景情况:
- 吊滴试验是测量液体界面张力的标准方法.
- 颗粒系统表现出类似于流体动力学的复杂行为,但具有明显的粒子级相互作用.
- 了解凝聚性颗粒聚合物对于从材料加工到地质现象的应用至关重要.
研究的目的:
- 为了研究凝聚性颗粒状集群的脱落动态从一个孔口.
- 确定影响分离颗粒状集群体体积的因素.
- 建立一个缩放规律,以颗粒状集群大小,并将其与液体悬浮滴.
主要方法:
- 一个经过修改的吊滴试验是使用密集的凝聚性油滴在水溶液中进行的.
- 脱离的颗粒状集群的体积是孔径大小和凝聚力强度的函数.
- 分析了粒子大小对集群体体积的影响.
主要成果:
- 发现颗粒集群体体积取决于孔径大小和粒子凝聚力.
- 平均集群体积没有显著地取决于单个滴滴的大小.
- 对于颗粒状集群大小来说,一个新的缩放定律得到了推导,与液态悬挂滴的定律不同.
结论:
- 凝聚性颗粒状集群从孔隙中脱离受到类似于液体悬浮滴的因素的控制,但有关键差异.
- 颗粒集群中的粒子重新排列的约束使它们无法达到最小的表面结构,与液滴不同.
- 已建立的缩放法为理解凝聚性颗粒性聚合物脱离提供了一个新的框架.
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